Preparation and Characterization of a Novel Composite of Chitosan/Shell Particles
文献类型：期刊论文
| 作者 | Zeng, MF; Zhang, X; Lu, CY; Qi, CZ; Wang, BY ; Wang BY(王宝义)
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| 刊名 | JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
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| 出版日期 | 2011 |
| 卷号 | 50期号:4页码:688-703 |
| 关键词 | chitosan free volume shell particles strength |
| 通讯作者 | [Zeng, Minfeng ; Zhang, Xin ; Lu, Cuiyun ; Qi, Chenze] Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Peoples R China ; [Wang, Baoyi] Chinese Acad Sci, Inst High Energy Phys, Beijing, Peoples R China |
| 英文摘要 | Nanometer sized (mean size: 433.9 nm) pearl shell particles (SP) were prepared with a ball mill. Thermal analysis and Fourier transform infrared (FTIR) results proved that the SP contained mainly CaCO(3) (about 95%) and a small organic phase (about 5%). Novel biodegradable composites based upon chitosan (CS) and SPs were prepared using an in situ precipitation method. The organic components of SP are highly compatible with both CS and glutaraldehyde (GA). The strength and modulus of CS gel rods, prepared by coagulation of a CS/SP/GA solution in NaOH, in both the dry and wet state, were improved remarkably with addition of appropriate amounts of SP together with GA. For example, with a composition of 3% SP and 0.3% GA added, the strength and modulus were 42.9 MPa and 1.41 GPa, increasing 75 and 464% compared with CS alone, respectively. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) results showed that GA acts as not only a crosslinking agent for CS, but also a compatibilizer for CS and SP. It was found that the modified rods have smaller free volume size but nearly the same free volume fraction as pure CS rods. The good interfacial adhesion and more compact microstructure can sensitively reflect the changes in the free volume of the composites. |
| 学科主题 | Polymer Science |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287498600005 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/238272]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zeng, MF,Zhang, X,Lu, CY,et al. Preparation and Characterization of a Novel Composite of Chitosan/Shell Particles[J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,2011,50(4):688-703. |
| APA | Zeng, MF,Zhang, X,Lu, CY,Qi, CZ,Wang, BY,&王宝义.(2011).Preparation and Characterization of a Novel Composite of Chitosan/Shell Particles.JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,50(4),688-703. |
| MLA | Zeng, MF,et al."Preparation and Characterization of a Novel Composite of Chitosan/Shell Particles".JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS 50.4(2011):688-703. |
入库方式： OAI收割
来源：高能物理研究所
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