Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS
文献类型：期刊论文
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| 作者 | Pei, ZG; Shan, XQ; Zhang, SZ; Kong, JJ; Wen, B; Zhang, J ; Zheng, LR; Xie, YN; Janssens, K; Zhang J(张静)
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| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 ; JOURNAL OF HAZARDOUS MATERIALS
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| 出版日期 | 2011 ; 2011 |
| 卷号 | 186期号:1页码:842-848 |
| 关键词 | Sorption Copper Norfloxacin EXAFS Montmorillonite Sorption Copper Norfloxacin EXAFS Montmorillonite |
| DOI | 10.1016/j.jhazmat.2010.11.076 |
| 通讯作者 | [Pei, Zhi-Guo ; Shan, Xiao-Quan ; Zhang, Shu-Zhen ; Kong, Jing-Jing ; Wen, Bei] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China ; [Kong, Jing-Jing] Fujian Normal Univ, Sch Chem & Mat, Fuzhou 350007, Peoples R China ; [Zhang, Jing ; Zheng, Li-Rong ; Xie, Ya-Ning] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing 100049, Peoples R China ; [Janssens, Koen] Univ Antwerp, Dept Chem, Ctr Micro & Trace Anal, B-2610 Antwerp, Belgium ; [Pei, Zhi-Guo ; Shan, Xiao-Quan ; Zhang, Shu-Zhen ; Kong, Jing-Jing ; Wen, Bei] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China ; [Kong, Jing-Jing] Fujian Normal Univ, Sch Chem & Mat, Fuzhou 350007, Peoples R China ; [Zhang, Jing ; Zheng, Li-Rong ; Xie, Ya-Ning] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing 100049, Peoples R China ; [Janssens, Koen] Univ Antwerp, Dept Chem, Ctr Micro & Trace Anal, B-2610 Antwerp, Belgium |
| 文献子类 | Article |
| 英文摘要 | Co-adsorption of norfloxacin (Nor) and Cu(II) on montmorillonite at pH 4.5, 7.0 and 9.0 was studied by integrated batch adsorption experiments and extended X-ray absorption fine structure (EXAFS) spectroscopy. Under such pH conditions the dominant species of Nor are cation (Nor(+)), zwitterion (Nor(+/-)), and anion (Nor(-)), respectively. Results indicated that Nor sorption decreased with an increase of solution pH. The presence of Cu(II) slightly suppressed the Nor(+) sorption at pH 4.5, while increased Nor(+/-) and Nor(-)sorption on montmorillonite at pH 7.0 and 9.0, respectively. In contrast, Nor increased Cu(II) adsorption at pH 4.5, but had little effect on the adsorption of Cu(II) on montmorillonite at pH 7.0 and 9.0. Spectroscopic results showed that, at pH 4.5, Nor(+) was sorbed on montmorillonite by the formation of outer-sphere montmorillonite-Nor-Cu(II) ternary surface complex. At pH 7.0, montmorillonite-Nor-Cu(II) and montmorillonite-Cu(II)-Nor ternary surface complexes co-exist. At pH 9.0, montmorillonite-Cu(II)-Nor ternary surface complex was likely formed, which was different to Cu(II)(Nor)(2) precipitate of the solution. (C) 2010 Elsevier B.V. All rights reserved.; Co-adsorption of norfloxacin (Nor) and Cu(II) on montmorillonite at pH 4.5, 7.0 and 9.0 was studied by integrated batch adsorption experiments and extended X-ray absorption fine structure (EXAFS) spectroscopy. Under such pH conditions the dominant species of Nor are cation (Nor(+)), zwitterion (Nor(+/-)), and anion (Nor(-)), respectively. Results indicated that Nor sorption decreased with an increase of solution pH. The presence of Cu(II) slightly suppressed the Nor(+) sorption at pH 4.5, while increased Nor(+/-) and Nor(-)sorption on montmorillonite at pH 7.0 and 9.0, respectively. In contrast, Nor increased Cu(II) adsorption at pH 4.5, but had little effect on the adsorption of Cu(II) on montmorillonite at pH 7.0 and 9.0. Spectroscopic results showed that, at pH 4.5, Nor(+) was sorbed on montmorillonite by the formation of outer-sphere montmorillonite-Nor-Cu(II) ternary surface complex. At pH 7.0, montmorillonite-Nor-Cu(II) and montmorillonite-Cu(II)-Nor ternary surface complexes co-exist. At pH 9.0, montmorillonite-Cu(II)-Nor ternary surface complex was likely formed, which was different to Cu(II)(Nor)(2) precipitate of the solution. (C) 2010 Elsevier B.V. All rights reserved. |
| 学科主题 | Engineering; Environmental Sciences & Ecology ; Engineering; Environmental Sciences & Ecology |
| 类目[WOS] | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| 研究领域[WOS] | Engineering ; Environmental Sciences & Ecology |
| URL标识 | 查看原文 |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 原文出处 | SCI |
| 语种 | 英语 ; 英语 |
| WOS记录号 | WOS:000288102400107 ; WOS:000288102400107 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/238587]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_实验物理中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Pei, ZG,Shan, XQ,Zhang, SZ,et al. Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS, Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS[J]. JOURNAL OF HAZARDOUS MATERIALS, JOURNAL OF HAZARDOUS MATERIALS,2011, 2011,186, 186(1):842-848, 842-848. |
| APA | Pei, ZG.,Shan, XQ.,Zhang, SZ.,Kong, JJ.,Wen, B.,...&谢亚宁.(2011).Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS.JOURNAL OF HAZARDOUS MATERIALS,186(1),842-848. |
| MLA | Pei, ZG,et al."Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS".JOURNAL OF HAZARDOUS MATERIALS 186.1(2011):842-848. |
入库方式： OAI收割
来源：高能物理研究所
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