Small angle x-ray scattering study on the conformation of polystyrene in toluene during adding anti-solvent CO2
文献类型:期刊论文
作者 | Liu, Y; Chen, DF; Wang, HL; Chen, N; Li, D; Han, BX; Rong, LX; Zhao, H; Wang, J; Dong, BZ |
刊名 | CHINESE PHYSICS |
出版日期 | 2002 |
卷号 | 11期号:10页码:1037-1041 |
关键词 | small angle x-ray scattering supercritical fluid anti-solvent process polystyrene |
通讯作者 | China Inst Atom Energy, Beijing 102413, Peoples R China ; Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing 100039, Peoples R China |
英文摘要 | The conformation of polystyrene in the anti-solvent process of supercritical fluids (compressed CO2 + polystyrene + toluene) has been studied by small angle x-ray scattering with synchrotron radiation as an x-ray source. Coil-to-globule transformation of the polystyrene chain was observed with the increase of the anti-solvent CO2 pressure; i.e. polystyrene coiled at a pressure lower than the cloud point pressure (P-c) and turned into a globule with a uniform density at pressures higher than P-c. Fractal behaviour was also found in the chain contraction, and the mass fractal dimension increased with increasing CO2 pressure. |
学科主题 | Physics |
类目[WOS] | Physics, Multidisciplinary |
研究领域[WOS] | Physics |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000178919000013 |
源URL | [http://ir.ihep.ac.cn/handle/311005/238937] |
专题 | 高能物理研究所_加速器中心 高能物理研究所_实验物理中心 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Liu, Y,Chen, DF,Wang, HL,et al. Small angle x-ray scattering study on the conformation of polystyrene in toluene during adding anti-solvent CO2[J]. CHINESE PHYSICS,2002,11(10):1037-1041. |
APA | Liu, Y.,Chen, DF.,Wang, HL.,Chen, N.,Li, D.,...&董宝中.(2002).Small angle x-ray scattering study on the conformation of polystyrene in toluene during adding anti-solvent CO2.CHINESE PHYSICS,11(10),1037-1041. |
MLA | Liu, Y,et al."Small angle x-ray scattering study on the conformation of polystyrene in toluene during adding anti-solvent CO2".CHINESE PHYSICS 11.10(2002):1037-1041. |
入库方式: OAI收割
来源:高能物理研究所
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