Correlations between the free-volume properties and the miscibility of chitosan/polar polymers blend membranes
文献类型：期刊论文
| 作者 | Zeng, MF; Sun, XD; Wang, Y ; Yao, XD; Xiao, HQ; Wang, BY; Qi, CZ; Wang BY(王宝义)
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| 刊名 | RADIATION PHYSICS AND CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 77期号:9页码:1062-1068 |
| 关键词 | Miscibility Free volume Positron annihilation Blends |
| 通讯作者 | [Zeng Minfeng ; Sun Xudong ; Wang Yun ; Yao Xiandong ; Xiao Huiquan ; Qi Chenze] Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Peoples R China ; [Wang Baoyi] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China |
| 英文摘要 | The miscibility of chitosan (CS)/polar polymer blend membranes has been studied by positron annihilation and other methods. The miscibility of these two blend systems (CS/polyvinyl pyrrolidone (PVP) and CS/polyethylene glycol (PEG)) is good in the solution state clue to the hydrogen interaction between the functional groups of the studied polymers. However, the miscibility of these two blend systems in the solid state is better in the CS/PVP system than in the CS/PEG system. The differences in miscibility of such two blend systems in the solid state were powerfully demonstrated with positron annihilation lifetime spectroscopy (PALS) methods. The CS/PEG blend system had Much larger free-volume size and lower free-volume concentration. For their poorer interaction and phase separation fact, the molecules in the interfacial zone of the CS/PEG blend Lire less compact than the CS matrix. Therefore. the free-volume size in the interfacial zone was much larger than it in the CS matrix. (C) 2008 Published by Elsevier Ltd. |
| 学科主题 | Chemistry; Nuclear Science & Technology; Physics |
| 类目[WOS] | Chemistry, Physical ; Nuclear Science & Technology ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Nuclear Science & Technology ; Physics |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260203500013 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/238980]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zeng, MF,Sun, XD,Wang, Y,et al. Correlations between the free-volume properties and the miscibility of chitosan/polar polymers blend membranes[J]. RADIATION PHYSICS AND CHEMISTRY,2008,77(9):1062-1068. |
| APA | Zeng, MF.,Sun, XD.,Wang, Y.,Yao, XD.,Xiao, HQ.,...&王宝义.(2008).Correlations between the free-volume properties and the miscibility of chitosan/polar polymers blend membranes.RADIATION PHYSICS AND CHEMISTRY,77(9),1062-1068. |
| MLA | Zeng, MF,et al."Correlations between the free-volume properties and the miscibility of chitosan/polar polymers blend membranes".RADIATION PHYSICS AND CHEMISTRY 77.9(2008):1062-1068. |
入库方式： OAI收割
来源：高能物理研究所
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