Modulation of structural and electronic properties of fullerene and metallofullerenes by surface chemical modifications
文献类型：期刊论文
| 作者 | Tang J(唐军); Xing GM(邢更妹) ; Zhao F(赵峰); Yuan H(袁慧); Zhao YL(赵宇亮); Tang, J; Xing, GM; Zhao, F; Yuan, H; Zhao, YL
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| 刊名 | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
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| 出版日期 | 2007 |
| 卷号 | 7期号:4-5页码:1085-1101 |
| 关键词 | fullerene metallofullerene nanotube electronic properties modulation chemical modification |
| 通讯作者 | Chinese Acad Sci, Lab Bioenvironm Hlth Sci Nanoscale Mat, Inst High Energy Phys, Beijing 100049, Peoples R China ; Natl Ctr Nanosci & Nanotechnol, Beijing 100080, Peoples R China ; Grad Univ, Chinese Acad Sci, Coll Chem, Beijing 100049, Peoples R China |
| 英文摘要 | Many applications of fullerene, metallofullerene, and carbon nanotubes request the chemical modifications. But how the modification influences the stability, structural, and electronic properties that directly relate to the practical functions of the carbon nanomaterials, this issue is discussed in this paper. The outer chemical modifications can sensitively influence the stability of final derivatives of fullerenes, depending on parameters such as the number of the modified groups, the unintended impurity groups on the cage surface, and chemical conditions in synthesizing processes. The outer chemical modification can induce alteration in electronic properties of metallofullerene. Gd@C(82) is taken as a model to show how the electronic properties of the encaged metal atom are modulated by the cage surface modification. There exist sandwich-type electronic interactions along pathway: [outer modification group]-[cage surface]-[inner atom], and their synergistic effects are discussed. Beside the number of the modified groups, whose distribution patterns on the cage surface also play crucial roles in determining how the electronic interactions are modulated. Their synergistic effects dominate the electronic, optical, or magnetic properties of functionalized fullerenic nanomaterials. As the surface of nanotube is chemically more inert as compared to that of fullerene or metallofullerene, to achieve desirable modulations of nanotubes is probably more difficult. The research aimed to explore the changes in their structural or electronic property after the outer chemical functionalization was few, though this is of special significant and needs investigations because the chemical modifications are widely applying to the carbon nanotubes in applications. |
| 学科主题 | Chemistry; Science & Technology - Other Topics; Materials Science; Physics |
| 类目[WOS] | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000245142200002 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/239023]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Tang J,Xing GM,Zhao F,et al. Modulation of structural and electronic properties of fullerene and metallofullerenes by surface chemical modifications[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2007,7(4-5):1085-1101. |
| APA | 唐军.,邢更妹.,赵峰.,袁慧.,赵宇亮.,...&Zhao, YL.(2007).Modulation of structural and electronic properties of fullerene and metallofullerenes by surface chemical modifications.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,7(4-5),1085-1101. |
| MLA | 唐军,et al."Modulation of structural and electronic properties of fullerene and metallofullerenes by surface chemical modifications".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 7.4-5(2007):1085-1101. |
入库方式： OAI收割
来源：高能物理研究所
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