Studies on structure and electrochemical properties of pillared M-MnO2 (M=Ba2+, Sr2+, ZrO2+)
文献类型：期刊论文
| 作者 | Lu, YL ; Yang, L; Wei, M; Xie, Y; Liu, T; Xie YN(谢亚宁); Liu T(刘涛)
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| 刊名 | JOURNAL OF SOLID STATE ELECTROCHEMISTRY
 |
| 出版日期 | 2007 |
| 卷号 | 11期号:9页码:1157-1162 |
| 关键词 | layered M-MnO2 cathode materials lithium secondary batteries intercalation electrochemical properties |
| 通讯作者 | Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China |
| 英文摘要 | Supramolecular pillared oxides M - MnO2 (M Ba2+; Sr2+; ZrO2+) were prepared through the intercalation of M2+ cations into a MnO2 host matrix by the method of ion exchange between the precursor delta-KxMnO2 and the corresponding guest. The materials M-MnO2 crystallize in the hexagonal system, the same structure as the precursor, with a larger interlamellar spacing. In the case of ZrO-MnO2, extended X-ray absorption fine structure (EXAFS) determination indicates that the Zr atom locates between the MnO2 layers forming a stable structure. Compared with the precursor, the cycling property of M-MnO2 was improved distinctly, while the capacity decreased to some degree due to the strong interaction between pillars and the host matrix. Among these pillared materials, ZrO-MnO2 has an advanced reversible capacity of 161.5 mAh center dot g(-1) and improved cycling behavior compared with the precursor. |
| 学科主题 | Electrochemistry |
| 类目[WOS] | Electrochemistry |
| 研究领域[WOS] | Electrochemistry |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248615100003 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/239123]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Lu, YL,Yang, L,Wei, M,et al. Studies on structure and electrochemical properties of pillared M-MnO2 (M=Ba2+, Sr2+, ZrO2+)[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2007,11(9):1157-1162. |
| APA | Lu, YL.,Yang, L.,Wei, M.,Xie, Y.,Liu, T.,...&刘涛.(2007).Studies on structure and electrochemical properties of pillared M-MnO2 (M=Ba2+, Sr2+, ZrO2+).JOURNAL OF SOLID STATE ELECTROCHEMISTRY,11(9),1157-1162. |
| MLA | Lu, YL,et al."Studies on structure and electrochemical properties of pillared M-MnO2 (M=Ba2+, Sr2+, ZrO2+)".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 11.9(2007):1157-1162. |
入库方式： OAI收割
来源：高能物理研究所
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