Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O
文献类型：期刊论文
| 作者 | Shao, K; Ma, Y; Chen, ZH; Zhang, XT; He, T; Yao, JN; Liu, T; Zhang, J ; Hu, TD; Liu T(刘涛)
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| 刊名 | ACTA CHIMICA SINICA
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| 出版日期 | 2001 |
| 卷号 | 59期号:8页码:1335-1339 |
| 关键词 | ethylenediammonium molybdate synthesis photochromic property |
| 通讯作者 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China ; Chinese Acad Sci, Inst High Energet Phys, Beijing 100039, Peoples R China |
| 英文摘要 | A novel photochromic compound NH3CH2CH2NH3Mo3O10.4.4H(2)O has been synthesized using ethylenediammonium cations as template under mild chemical conditions. Elemental analysis, TGA curve and IR spectra show that its inorganic framework is constructed from infinite chains of (Mo3O10)(infinity)(2-). Ethylenediammonium cations are bounded to the inorganic chain structure through a supramolecular interaction. It is found that this compound has good photochromic property. Differing from vacuum deposited MoO3 film, this compound turns from white to reddish brown after UV irradiation. EXAFS spectra confirm proton transfer from ethylenediammonium cations to Mo-O- after UV irradiation. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000170513100030 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/239289]  |
| 专题 | 高能物理研究所_实验物理中心 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Shao, K,Ma, Y,Chen, ZH,et al. Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O[J]. ACTA CHIMICA SINICA,2001,59(8):1335-1339. |
| APA | Shao, K.,Ma, Y.,Chen, ZH.,Zhang, XT.,He, T.,...&胡天斗.(2001).Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O.ACTA CHIMICA SINICA,59(8),1335-1339. |
| MLA | Shao, K,et al."Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O".ACTA CHIMICA SINICA 59.8(2001):1335-1339. |
入库方式： OAI收割
来源：高能物理研究所
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