EXAFS study of Ni/W/Zeolite/Al2O3 hydrocracking catalyst sulfurized with different modified zeolites
文献类型：期刊论文
| 作者 | Zhang, J ; Lu, HL; Sun, JW; Yao, JD; Li, QZ; Guan, MH; Wang, JF; Ding, LH; Yin, ZQ; Hu, TD
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| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2000 |
| 卷号 | 21期号:10页码:1459-1463 |
| 关键词 | hydrocracking catalyst zeolites EXAFS NiWS phase |
| 通讯作者 | Fudan Univ, Dept Chem, Shanghai 200437, Peoples R China ; Fushun Petr Res Inst, Fushun 113001, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing 100039, Peoples R China |
| 英文摘要 | Four hydrocracking catalysts supported on different kinds of modified Y zeolites were studied by utilizing EXAFS (Extend X-ray Absorption Fine Structure). The results show that the Ni and W in the catalysts have not been thoroughly sulfided. Apart from the sulfided state, the tungsten in the sulfided catalysts exists in a state of oxosulfided tungsten while some nickels exist in their oxide state. In addition, it also shows that there are NiWS species in the sulfided catalysts and the amount of which shows a good correlation with the Bronsted acid sites of the mixture supports of zeolites and gamma-Al2O3. It means that the NiWS species maybe exist mainly in the cavities of the zeolites and the tungsten in micropore zeolites is more difficult to be sulfided than that on the surface of amorphous Al2O3. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000089885400003 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/239366]  |
| 专题 | 中国科学院高能物理研究所_中国散裂中子源 高能物理研究所_实验物理中心 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, J,Lu, HL,Sun, JW,et al. EXAFS study of Ni/W/Zeolite/Al2O3 hydrocracking catalyst sulfurized with different modified zeolites[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2000,21(10):1459-1463. |
| APA | Zhang, J.,Lu, HL.,Sun, JW.,Yao, JD.,Li, QZ.,...&谢亚宁.(2000).EXAFS study of Ni/W/Zeolite/Al2O3 hydrocracking catalyst sulfurized with different modified zeolites.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,21(10),1459-1463. |
| MLA | Zhang, J,et al."EXAFS study of Ni/W/Zeolite/Al2O3 hydrocracking catalyst sulfurized with different modified zeolites".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 21.10(2000):1459-1463. |
入库方式： OAI收割
来源：高能物理研究所
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