The interaction of Cu2+ ions and NaDC micelles
文献类型：期刊论文
| 作者 | Sun, Y; Yang, ZL; Zhang, L; Hu, TD ; Soloway, RD; Weng, SF; Wu, JG; Hu TD(胡天斗)
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| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2002 |
| 卷号 | 58期号:7页码:1489-1498 |
| 关键词 | copper deoxycholate sodium deoxycholate steroid micelle gel FT-IR spectra |
| 通讯作者 | Peking Univ, Dept Chem, Beijing 100871, Peoples R China ; Acad Sinica, Inst High Energy Phys, Beijing 100089, Peoples R China ; Univ Texas, Med Branch, Dept Internal Med, Div Gastroenterol, Galveston, TX 77555 USA |
| 英文摘要 | By mixing an aqueous solution of CuCl2 with an NaDC aqueous solution of various concentration and initial molar ratio, seven coordinated samples with distinct appearances and characters were obtained. Their structures and components were investigated by FT-IR spectroscopy, EXAFS (the extended X-ray absorption fine structure), thermal analysis, X-ray diffraction, laser light scattering, TEM (transmission electron micrograph), element analysis and ICP (inductively coupled plasma) analysis. The following conclusions were given: (1) The complexes of Cu2+-NaDC with distinct appearances and properties were synthesized. (2) After Cu(DC)(2) dissolved in NaDC aqueous solution, larger micelles (30-90 nm diameter) formed in the supernate, it is a mixed micelle with Cu(DC)(2) and NaDC. So these micelles are a new kind of micelle containing two kinds of metal ions. This is a new result using metal ions as bridges to form micelle. (3) According to the different concentration of Cu2+ to NaDC, the complexes formed as gel or poly-crystals. Both the composition of gel complexes and the coordination structure of carboxyl groups with metal ions varied with the initial molar ratio of Cu2+ to Na+. The gel complexes exhibits the non-stoichiometric character. (4) These results are in agreement with physiological condition. All the different states such as gel, precipitate, micelles of various structures are present in bile of gallbladder. We can suggest an ideal model of the interaction between Cu2+ and bile salts in vivo. (C) 2002 Elsevier Science B.V. All rights reserved. |
| 学科主题 | Spectroscopy |
| 类目[WOS] | Spectroscopy |
| 研究领域[WOS] | Spectroscopy |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000175656500016 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/239380]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Sun, Y,Yang, ZL,Zhang, L,et al. The interaction of Cu2+ ions and NaDC micelles[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2002,58(7):1489-1498. |
| APA | Sun, Y.,Yang, ZL.,Zhang, L.,Hu, TD.,Soloway, RD.,...&胡天斗.(2002).The interaction of Cu2+ ions and NaDC micelles.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,58(7),1489-1498. |
| MLA | Sun, Y,et al."The interaction of Cu2+ ions and NaDC micelles".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 58.7(2002):1489-1498. |
入库方式： OAI收割
来源：高能物理研究所
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