Superconcentrated Hydrochloric Acid
文献类型：期刊论文
| 作者 | Huang, K; Zhou, H; He, AQ; Sun, Y; Liu, YF; Gao, XX; Zhao, Y; Liu, SX; Li, ZH ; Hu, TD
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| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
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| 出版日期 | 2011 |
| 卷号 | 115期号:24页码:7823-7829 |
| 通讯作者 | [Sun, Yan ; Li, Xiaopei ; Liu, Cuige ; Wei, Yongju] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China ; [Huang, Kun ; Zhou, Hui ; He, Anqi ; Sun, Yan ; Liu, Yufeng ; Gao, Xiuxiang ; Liu, Shaoxuan ; Li, Xiaopei ; Yang, Zhanlan ; Xu, Yizhuang ; Wu, Jinguang] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China ; [Zhou, Hui ; Cai, Yuanli] Soochow Univ, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Dept Polymer Sci & Engn, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China ; [Liu, Yufeng ; Zhao, Ying] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China ; [Li, Zhihong ; Hu, Tiandou] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Yang, Limin] Peking Univ, State Key Lab Nucl Phys & Technol, Inst Heavy Ion Phys, Sch Phys, Beijing 100871, Peoples R China ; [Feng, Juan] Univ Elect Sci & Technol China, Sch Life Sci & Technol, Chengdu 610054, Peoples R China ; [Noda, Isao] Procter & Gamble Co, W Chester, OH 45069 USA |
| 英文摘要 | We report the discovery of a potentially useful superconcentrated HCl at ambient temperature and pressure by using a simple surfactant-based reversed micelle system. Surprisingly, the molar ratios of H(+) to H(2)O (denoted as n(H+)/n(H2O)) in superconcentrated HCl can be larger than 5, while the maximum achievable n(H+)/n(H2O) value for conventional saturated HCl aqueous solution (37 wt %) is only about 0.28. Furthermore, both NMR and FT-IR results indicate that a significant amount of HCl remains in the molecular form rather than being ionized into H(+) and Cl(-). The superconcentrated HCl may promote some organic reactions that are not feasible by using conventional 37 wt % HCl solution. For example, addition reaction between C=C and HCl occurs in superconcentrated HCl solution without using catalysts. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291709500013 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/240133]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_加速器中心 中国科学院高能物理研究所 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Huang, K,Zhou, H,He, AQ,et al. Superconcentrated Hydrochloric Acid[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(24):7823-7829. |
| APA | Huang, K.,Zhou, H.,He, AQ.,Sun, Y.,Liu, YF.,...&胡天斗.(2011).Superconcentrated Hydrochloric Acid.JOURNAL OF PHYSICAL CHEMISTRY B,115(24),7823-7829. |
| MLA | Huang, K,et al."Superconcentrated Hydrochloric Acid".JOURNAL OF PHYSICAL CHEMISTRY B 115.24(2011):7823-7829. |
入库方式： OAI收割
来源：高能物理研究所
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