Luminescent metastable Y2WO6:Ln(3+) (Ln = Eu, Er, Sm, and Dy) microspheres with controllable morphology via self-assembly
文献类型:期刊论文
作者 | Wang, JA; Zhang, ZJ; Zhao, JT![]() ![]() ![]() ![]() ![]() |
刊名 | JOURNAL OF MATERIALS CHEMISTRY
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出版日期 | 2010 |
卷号 | 20期号:48页码:10894-10900 |
通讯作者 | [Wang, Jiao ; Zhang, Zhi-Jun ; Zhao, Jing-Tai ; Chen, Hao-Hong ; Yang, Xin-Xin] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent Optofunct Inorgan Mat, Shanghai 200050, Peoples R China ; [Wang, Jiao ; Zhang, Zhi-Jun] Sch Chinese Acad Sci, Beijing 100039, Peoples R China ; [Tao, Ye ; Huang, Yan] Chinese Acad Sci, Inst High Energy Phys, Beijing 100039, Peoples R China |
英文摘要 | Three-dimensional (3D) Y2WO6 and Y2WO6:Ln(3+) microspheres with novel controllable morphology have been obtained by the hierarchical self-assembly via a hydrothermal synthesis route with a subsequent heat treatment. The amount of citric acid and polyvinylpyrrolidone (PVP) play crucial roles in the controlling of the morphologies. Hollow, core/shell as well as waxberry-shape Y2WO6 microspheres can be prepared in different reaction systems under the same facile hydrothermal conditions. Metastable phases of the samples form when they are crystallized at low temperature, which transfer to the thermodynamically stable counterpart above 1100 degrees C. This phase transformation is irreversible. The mechanism of reaction and self-assembly evolution process are proposed. The as-prepared Y2WO6:Ln(3+) (Ln = Eu, Er, Sm, and Dy) samples show strong multi-color visible light emission under ultraviolet-visible light excitation. Compared with the monoclinic one, this metastable Y2WO6:Eu3+ phase exhibits different luminescent properties. Due to multi-color luminescent properties, these Ln(3+)-doped (Ln = Eu, Er, Sm, and Dy) metastable Y2WO6 morophologies controllable microspherical samples may be promising for further fundamental research and find applications in color displays. |
学科主题 | Chemistry; Materials Science |
类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Materials Science |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000284773100019 |
源URL | [http://ir.ihep.ac.cn/handle/311005/240175] ![]() |
专题 | 高能物理研究所_多学科研究中心 高能物理研究所_理论物理室 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Wang, JA,Zhang, ZJ,Zhao, JT,et al. Luminescent metastable Y2WO6:Ln(3+) (Ln = Eu, Er, Sm, and Dy) microspheres with controllable morphology via self-assembly[J]. JOURNAL OF MATERIALS CHEMISTRY,2010,20(48):10894-10900. |
APA | Wang, JA.,Zhang, ZJ.,Zhao, JT.,Chen, HH.,Yang, XX.,...&黄艳.(2010).Luminescent metastable Y2WO6:Ln(3+) (Ln = Eu, Er, Sm, and Dy) microspheres with controllable morphology via self-assembly.JOURNAL OF MATERIALS CHEMISTRY,20(48),10894-10900. |
MLA | Wang, JA,et al."Luminescent metastable Y2WO6:Ln(3+) (Ln = Eu, Er, Sm, and Dy) microspheres with controllable morphology via self-assembly".JOURNAL OF MATERIALS CHEMISTRY 20.48(2010):10894-10900. |
入库方式: OAI收割
来源:高能物理研究所
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