X-ray absorption near-edge structure at the Mg and FeK edges in olivine minerals
文献类型:期刊论文
作者 | Wu ZY(吴自玉)![]() ![]() |
刊名 | PHYSICAL REVIEW B
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出版日期 | 2004 |
卷号 | 69期号:10页码:104106 |
通讯作者 | Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China ; Ist Nazl Fis Nucl, Lab Nazl Frascati, I-00044 Frascati, RM, Italy ; Univ Roma Tre, Dipartimento Sci Geol, I-00146 Rome, RM, Italy ; Univ Camerino, Dipartimento Sci Terra, I-62032 Camerino, MC, Italy |
英文摘要 | Mg and Fe K-edge x-ray absorption near-edge spectroscopy spectra of the Pbnm olivine series end members forsterite, fayalite, monticellite, and kirschsteinite, as well as of a synthetic Fe-Mg olivine of intermediate composition (Fo50), have been recorded and compared with multiple-scattering simulations. A comparison of experimental and theoretical spectra shows that all transition features, energy positions, and relative intensities can be reproduced in the energy range up to 60 eV above threshold when using clusters containing at least 80 atoms and extending over a sphere at least 0.6 nm in radius away from the absorber. Mg and Fe are entirely in the expected structural sites in the four investigated end members. None of the models of Mg and Fe ordering in the octahedral site for the Fe50 olivine compound proposed so far is verified; thus Fe-Mg ordering still remains an open problem for olivines of intermediate compositions. |
学科主题 | Physics |
类目[WOS] | Physics, Condensed Matter |
研究领域[WOS] | Physics |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000220813500025 |
源URL | [http://ir.ihep.ac.cn/handle/311005/240914] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Wu ZY,Wu, ZY,Mottana, A,et al. X-ray absorption near-edge structure at the Mg and FeK edges in olivine minerals[J]. PHYSICAL REVIEW B,2004,69(10):104106. |
APA | 吴自玉.,Wu, ZY.,Mottana, A.,Marcelli, A.,Paris, E.,...&Cibin, G.(2004).X-ray absorption near-edge structure at the Mg and FeK edges in olivine minerals.PHYSICAL REVIEW B,69(10),104106. |
MLA | 吴自玉,et al."X-ray absorption near-edge structure at the Mg and FeK edges in olivine minerals".PHYSICAL REVIEW B 69.10(2004):104106. |
入库方式: OAI收割
来源:高能物理研究所
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