Concentration characteristics of extractable organohalogens in PM2.5 and PM10 in Beijing, China
文献类型:期刊论文
作者 | Xu DD(徐殿斗); Song Y(宋炎); Chai ZF(柴之芳); Xu, DD; Dan, M; Song, Y; Chai, ZF; Zhuang, GS |
刊名 | ATMOSPHERIC ENVIRONMENT |
出版日期 | 2005 |
卷号 | 39期号:22页码:4119-4128 |
关键词 | organochlorinated pesticides polychlorinated biphenyls instrumental neutron activation analysis extractable organochlorine |
通讯作者 | Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Analyt Techn, Beijing 100049, Peoples R China ; Beijing Normal Univ, Atmospher Sci Res Ctr, Beijing 100875, Peoples R China |
英文摘要 | PM2.5 and PM10 samples were simultaneously collected at a downtown site in Beijing from May 2002 to April 2003 and analyzed by instrumental neutron activation analysis (INAA) and gas chromatography (GC) combined with organic solvent extraction method for the concentrations and distributions of extractable organohalogens (EOX), including extractable organo-chlorine (EOCl), -bromine (EOBr) and -iodine compounds (EOI), and organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs). The concentrations of EOX were increasing in the order of EOCl >> EOBr similar to EOI. EOCl accounted for 73-88% and 69-91% of EOX in PM2.5 and PM 10, respectively, suggesting that EOCl was the major component of the organohalogens in the atmosphere. The relative proportions of the known organochlorines (such as HCHs, DDTs, chlordanes, and PCBs) to total EOCl were 0.04-0.7% and 0.06-0.3% in PM2.5 and PM10, respectively, which implied that most of EOCl measured in aerosol was unknown. The ratios of alpha/gamma-HCH (0.9-1.5) and p,p'-DDE + DDD/p,p'-DDT (0.2-0.5) revealed the presence of the recent use of lindane and DDTs or impure dicofol in Beijing. In the plots of the logarithm of the OCPs concentrations versus reciprocal temperature (1/T), their linear relations were observed for PM2.5, which could be partly explained by temperature differences, but poor linearity for PM10. (c) 2005 Elsevier Ltd. All rights reserved. |
学科主题 | Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences |
类目[WOS] | Environmental Sciences ; Meteorology & Atmospheric Sciences |
研究领域[WOS] | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000230825400016 |
源URL | [http://ir.ihep.ac.cn/handle/311005/239961] |
专题 | 高能物理研究所_院士 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Xu DD,Song Y,Chai ZF,et al. Concentration characteristics of extractable organohalogens in PM2.5 and PM10 in Beijing, China[J]. ATMOSPHERIC ENVIRONMENT,2005,39(22):4119-4128. |
APA | 徐殿斗.,宋炎.,柴之芳.,Xu, DD.,Dan, M.,...&Zhuang, GS.(2005).Concentration characteristics of extractable organohalogens in PM2.5 and PM10 in Beijing, China.ATMOSPHERIC ENVIRONMENT,39(22),4119-4128. |
MLA | 徐殿斗,et al."Concentration characteristics of extractable organohalogens in PM2.5 and PM10 in Beijing, China".ATMOSPHERIC ENVIRONMENT 39.22(2005):4119-4128. |
入库方式: OAI收割
来源:高能物理研究所
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