Tough polypseudorotaxane supramolecular hydrogels with dual-responsive shape memory properties
文献类型：期刊论文
| 作者 | Feng W ; Zhou WF; Dai ZH; Yasin A; Yang HY; Yang, HY (reprint author), Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China.
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY B
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| 出版日期 | 2016 |
| 卷号 | 4期号:11页码:1924-1931 |
| ISSN号 | 2050-750X |
| DOI | 10.1039/c5tb02737c |
| 产权排序 | [Feng, Wei; Yasin, Akram; Yang, Haiyang] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China; [Zhou, Wanfu] Daqing Oilfield Co Ltd, Oilfield Prod Technol Inst, Daqing 163514, Peoples R China; [Dai, Zhaohe] Chinese Acad Sci, Inst Mech, Beijing 100190, Peoples R China |
| 文献子类 | 期刊论文 |
| 英文摘要 | Cyclodextrin-polypseudorotaxane hydrogels have attracted extensive attention for their potential application in biomedical fields. Herein, we develop a facile strategy for the in situ formation of mechanically tough polypseudorotaxane hydrogels through photoinitiated copolymerization of poly(ethylene glycol) methyl ether methacrylate, acrylamide and sodium acrylate in alpha-CD solution at 60 degrees C. For the first time, we manage to screen the host-guest interaction between alpha-CD and PEG before copolymerization in the presence of a temporary hydrogen bonding weakening monomer (acrylamide) at a suitable temperature (60 degrees C). This shielding effect weakens gradually during polymerization, thus leading to the formation of polypseudorotaxane aggregations and a tough physical hydrogel. The hydrogel can bear a large compressive strain (80%) without rupture, and exhibits excellent antifatigue properties. Furthermore, this hydrogel could be endowed with thermal/ascorbic acid activated shape memory performance after being treated with FeCl3 solution. This simple method will contribute to the design and application of smart supramolecular hydrogels. |
| 分类号 | 二类 |
| URL标识 | 查看原文 |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000372231800001 |
| 资助机构 | We gratefully acknowledge financial support from the National Natural Science Foundation of China (Grant no. 51273189) and the National Science and Technology Major Project of the Ministry of Science and Technology of China (2011ZX05010-003). |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/59546]  |
| 专题 | 力学研究所_流固耦合系统力学重点实验室(2012-) |
| 通讯作者 | Yang, HY (reprint author), Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Feng W,Zhou WF,Dai ZH,et al. Tough polypseudorotaxane supramolecular hydrogels with dual-responsive shape memory properties[J]. JOURNAL OF MATERIALS CHEMISTRY B,2016,4(11):1924-1931. |
| APA | Feng W,Zhou WF,Dai ZH,Yasin A,Yang HY,&Yang, HY .(2016).Tough polypseudorotaxane supramolecular hydrogels with dual-responsive shape memory properties.JOURNAL OF MATERIALS CHEMISTRY B,4(11),1924-1931. |
| MLA | Feng W,et al."Tough polypseudorotaxane supramolecular hydrogels with dual-responsive shape memory properties".JOURNAL OF MATERIALS CHEMISTRY B 4.11(2016):1924-1931. |
入库方式： OAI收割
来源：力学研究所
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