The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP
文献类型：期刊论文
| 作者 | Jiang XY(姜秀玉); Jiang X(江雪); Lu GL(陆国林); Feng C(冯纯); Huang XY(黄晓宇) |
| 刊名 | Polym. Chem.
 |
| 出版日期 | 2014 |
| 卷号 | 5期号:17页码:4915-4925 |
| 其他题名 | The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP |
| 通讯作者 | 陆国林 ; 黄晓宇 |
| 英文摘要 | A series of well-defined amphiphilic graft copolymers consisting of a hydrophilic poly(2-hydroxyethyl acrylate) (PHEA) backbone and hydrophobic polystyrene side chains were synthesized by the combination of reversible addition-fragmentation chain transfer (RAFT) polymerization, atom transfer radical polymerization (ATRP), and the grafting-from strategy. A new actylate monomer containing an ATRP initiating group, 2-hydroxyethyl 2-[(2-chloropropanoyloxy)methyl]acrylate, was first prepared via a four-step procedure using 2-hydroxyethyl acrylate as a starting material. This monomer was then RAFT homopolymerized to give a PHEA-based homopolymer bearing a Cl-containing ATRP initiating group in every repeating unit with a narrow molecular weight distribution (M-w/M-n = 1.08). This homopolymer directly initiated the ATRP of styrene to afford the desired well-defined poly(2-hydroxyethyl acrylate)graft-polystyrene graft copolymers (M-w/M-n <= 1.30) containing a hydroxyl in every repeating unit of the backbone without polymeric functionality transformation. The self-assembly behavior of the amphiphilic graft copolymers obtained was investigated by dynamic light scattering and transmission electron microscopy. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c4py00415a |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38899]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Jiang XY,Jiang X,Lu GL,et al. The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP[J]. Polym. Chem.,2014,5(17):4915-4925. |
| APA | 姜秀玉,江雪,陆国林,冯纯,&黄晓宇.(2014).The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP.Polym. Chem.,5(17),4915-4925. |
| MLA | 姜秀玉,et al."The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP".Polym. Chem. 5.17(2014):4915-4925. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。