Click synthesis of graphene/poly(N-(2-hydroxypropyl) methacrylamide) nanocomposite via "grafting-onto" strategy at ambient temperature
文献类型：期刊论文
| 作者 | Liu ZZ(刘站站)1; Lu GL(陆国林)1; Li YJ(李永军)1; Li YS(李永生)1; Huang XY(黄晓宇)1 |
| 刊名 | RSC Adv.
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:105页码:60920-60928 |
| 其他题名 | Click synthesis of graphene/poly(N-(2-hydroxypropyl) methacrylamide) nanocomposite via "grafting-onto" strategy at ambient temperature |
| 通讯作者 | 李永生 ; 黄晓宇 |
| 英文摘要 | So far, much work has been performed to modify graphene by physical or chemical methods, aiming to improve its solubility in solvents for its further application. Herein, we reported a new graphene/polymer nanocomposite, a graphene/poly(N-(2-hydroxypropyl) methacrylamide) (PHPMA) nanocomposite (G-PHPMA), by combining reversible addition-fragmentation chain transfer (RAFT) polymerization and click chemistry under mild conditions via the "grafting-onto" strategy. The as-prepared azido-terminated PHPMA homopolymer via RAFT polymerization was grafted onto yne-containing graphene through click chemistry at room temperature using CuBr/PMDETA as the catalytic system. FT-IR, XRD, Raman, element analysis, TGA, AFM, and TEM measurements were used to confirm the covalent linkage between PHPMA chains and graphene. The resulting G-PHPMA nanocomposite showed excellent dispersibility in organic solvents and aqueous media and it could quickly enter into SMMC-7721 and SH-SY5Y cells. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c4ra07825j |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38915]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 作者单位 | 1.中科院上海有机化学研究所 2.华东理工大学 |
| 推荐引用方式 GB/T 7714 | Liu ZZ,Lu GL,Li YJ,et al. Click synthesis of graphene/poly(N-(2-hydroxypropyl) methacrylamide) nanocomposite via "grafting-onto" strategy at ambient temperature[J]. RSC Adv.,2014,4(105):60920-60928. |
| APA | 刘站站,陆国林,李永军,李永生,&黄晓宇.(2014).Click synthesis of graphene/poly(N-(2-hydroxypropyl) methacrylamide) nanocomposite via "grafting-onto" strategy at ambient temperature.RSC Adv.,4(105),60920-60928. |
| MLA | 刘站站,et al."Click synthesis of graphene/poly(N-(2-hydroxypropyl) methacrylamide) nanocomposite via "grafting-onto" strategy at ambient temperature".RSC Adv. 4.105(2014):60920-60928. |
入库方式： OAI收割
来源：上海有机化学研究所
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