A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums
文献类型:期刊论文
作者 | Ge GC(葛广存); Huang XJ(黄小军); Ding CH(丁昌华); Wan SL(万世力); Dai LX(戴立信); Hou XL(侯雪龙) |
刊名 | Chem. Commun.
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出版日期 | 2014 |
卷号 | 50期号:23页码:3048-3051 |
其他题名 | 一种通过CuBr催化高炔丙胺的串联反应构建C=C-CF3片段的新策略: 高效合成含三氟甲基的切块4-三氟甲基-3,4-二氢吡咯盐 |
通讯作者 | 丁昌华 ; 侯雪龙 |
英文摘要 | A new strategy for the construction of a C=C-CF3 subunit has been developed via CuBr-catalyzed domino cyclization-trifluoromethylation of homopropargyl amines with Umemoto's reagent. 4-Trifluoromethyl-2,3- dihydro-pyrroliums were produced in high yields. The usefulness of these products has been demonstrated by the transformation of them into various other trifluoromethylated molecules. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c3cc49059a |
语种 | 英语 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39038] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Ge GC,Huang XJ,Ding CH,et al. A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums[J]. Chem. Commun.,2014,50(23):3048-3051. |
APA | 葛广存,黄小军,丁昌华,万世力,戴立信,&侯雪龙.(2014).A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.Chem. Commun.,50(23),3048-3051. |
MLA | 葛广存,et al."A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums".Chem. Commun. 50.23(2014):3048-3051. |
入库方式: OAI收割
来源:上海有机化学研究所
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