Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics
文献类型：期刊论文
| 作者 | Quan YJ(全杨健)1; Qiu ZZ(邱早早)1; Xie ZW(谢作伟)1 |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2014 |
| 卷号 | 136期号:21页码:7599-7602 |
| 其他题名 | 过渡金属介导三组份串联反应: 碳硼烷硼与芳烃间硼-碳(sp2)偶联及碳硼烷并三环化合物的合成 |
| 通讯作者 | 谢作伟 |
| 英文摘要 | Zirconium/nickel comediated one-pot three-component cascade cyclization of carboryne, alkene, and 2-bromophenyltrimethylsilylacetylene has been achieved, leading to the formation of a series of C,C,B-substituted carborane-fused tricyclics. On the basis of experimental results, a plausible mechanism is proposed including [2 + 2 + 1] cross-cyclotrimerization followed by intramolecular direct selective cage B-C(sp(2)) coupling. This represents the first example of direct cage B-C(phenyl) coupling via cage B-H activation. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja503489b |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39063]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.香港中文大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Quan YJ,Qiu ZZ,Xie ZW. Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics[J]. J. Am. Chem. Soc.,2014,136(21):7599-7602. |
| APA | 全杨健,邱早早,&谢作伟.(2014).Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics.J. Am. Chem. Soc.,136(21),7599-7602. |
| MLA | 全杨健,et al."Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics".J. Am. Chem. Soc. 136.21(2014):7599-7602. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。