Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions
文献类型：期刊论文
| 作者 | Ye KY(叶克印); Dai LX(戴立信); You SL(游书力) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2014 |
| 卷号 | 20期号:11页码:3040-3044 |
| 其他题名 | 通过铱催化的烯丙基胺化/过渡金属催化环化反应区域选择性以及对映选择性地合成N-烯丙基吲哚 |
| 通讯作者 | 游书力 |
| 英文摘要 | Regio- and enantioselective synthesis of N-allylindoles was realized through an iridium-catalyzed asymmetric allylic amination reaction with 2-alkynylanilines and subsequent transition-metal-catalyzed cyclization reactions. The highly enantioenriched allylic amines prepared from Ir-catalysis were treated with catalytic amount of NaAuCl(4)2H(2)O or PdCl2 providing various substituted N-allylindoles in excellent yields and enantioselectivities. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201400026 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39065]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Ye KY,Dai LX,You SL. Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions[J]. Chem.-Eur. J.,2014,20(11):3040-3044. |
| APA | 叶克印,戴立信,&游书力.(2014).Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions.Chem.-Eur. J.,20(11),3040-3044. |
| MLA | 叶克印,et al."Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions".Chem.-Eur. J. 20.11(2014):3040-3044. |
入库方式： OAI收割
来源：上海有机化学研究所
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