Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations
文献类型：期刊论文
| 作者 | Zhang J(张洁)1; Qiu ZZ(邱早早)1; Xu PF(许鹏飞)1; Xie ZW(谢作伟)1 |
| 刊名 | ChemPlusChem
 |
| 出版日期 | 2014 |
| 卷号 | 79期号:7页码:1044-1052 |
| 其他题名 | 碳硼炔与富烯的D-A反应: 碳硼烷并冰片烯的合成与转化 |
| 通讯作者 | 邱早早 ; 许鹏飞 |
| 英文摘要 | o-Carboryne (1,2-dehydro-o-carborane) generated in situ from the precursor 1-iodo-2-lithio-o-carborane reacts with 6,6'-diarylfulvenes to give a series of carboranonorbornadienes in moderate yields with excellent regioselectivity. The resultant [4+2] cycloadducts can be further derivatized, thus leading to the formation of a variety of highly functionalized carboranes. This study shows that such Diels-Alder reaction serves as a convenient method for the preparation of a new class of multifunctionalized o-carborane derivatives that might find applications in medicine and materials science. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cplu.201402129 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39082]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所 2.兰州大学 3.香港中文大学 |
| 推荐引用方式 GB/T 7714 | Zhang J,Qiu ZZ,Xu PF,et al. Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations[J]. ChemPlusChem,2014,79(7):1044-1052. |
| APA | 张洁,邱早早,许鹏飞,&谢作伟.(2014).Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations.ChemPlusChem,79(7),1044-1052. |
| MLA | 张洁,et al."Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations".ChemPlusChem 79.7(2014):1044-1052. |
入库方式： OAI收割
来源：上海有机化学研究所
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