Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination
文献类型：期刊论文
| 作者 | Chu JX(楚甲祥)1; Han XH(韩向豪)1; KEFALIDIS CHRISTOS E1; Zhou JL(周吉亮)1; MARON LAURENT1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1 |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2014 |
| 卷号 | 136期号:31页码:10894-10897 |
| 其他题名 | 路易斯酸对一个路易斯碱稳定的钪末端氮宾反应性的激活: C-H键活化, 环加成和脱氟化氢 |
| 通讯作者 | MARON LAURENT ; 陈耀峰 |
| 英文摘要 | A stable scandium-terminal imido complex is activated by borane to form an unsaturated terminal imido complex by removing the coordinated Lewis base, 4-(dimethylamino)pyridine, from the metal center. The ensuing terminal imido intermediate can exist as a THF adduct and/or undergo cycloaddition reaction with an internal alkyne, C-H activation of a terminal alkene, and dehydrofluorination of fluoro-substituted benzenes or alkanes at room temperature. DFT investigations further highlight the ease of C-H activation for terminal alkene and fluoroarene. They also shed light on the mechanistic aspects of these two reactions. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja5061559 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39083]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所 2.法国图卢兹第三大学 |
| 推荐引用方式 GB/T 7714 | Chu JX,Han XH,KEFALIDIS CHRISTOS E,et al. Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination[J]. J. Am. Chem. Soc.,2014,136(31):10894-10897. |
| APA | 楚甲祥.,韩向豪.,KEFALIDIS CHRISTOS E.,周吉亮.,MARON LAURENT.,...&陈耀峰.(2014).Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination.J. Am. Chem. Soc.,136(31),10894-10897. |
| MLA | 楚甲祥,et al."Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C-H Bond Activation, Cycloaddition, and Dehydrofluorination".J. Am. Chem. Soc. 136.31(2014):10894-10897. |
入库方式： OAI收割
来源：上海有机化学研究所
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