Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation
文献类型：期刊论文
| 作者 | Chu JX(楚甲祥); Zhou QH(周庆海); Li YX(李玉学); Leng XB(冷雪冰); Chen YF(陈耀峰) |
| 刊名 | Sci. China-Chem.
 |
| 出版日期 | 2014 |
| 卷号 | 57期号:8页码:1098-1105 |
| 其他题名 | 钪末端氮宾配合物诱导C-N键的活化和转化 |
| 通讯作者 | 李玉学 ; 陈耀峰 |
| 英文摘要 | The scandium terminal imido complex supported by a monoanionic tetradentate NNNN ligand, [LSc=N(DIPP)] (L = [MeC(N(DIPP))CHC(Me)(NCH2CH2N(Me)CH2CH2NMe2](-), DIPP = 2,6-( (i) Pr)(2)C6H3) (1), undergoes a C-N bond cleavage at elevated temperature to give a mononuclear scandium anilido intermediate 2a, which subsequently aggregates into a binuclear scandium anilido complex 2. The mononuclear intermediate 2a reacts with alkyne or imine to provide two scandium anilido complexes 3 and 4, which contain a dianionic tetradentate NNNC ligand or a dianionic tetradentate NNNN ligand. DFT calculations on the reaction mechanism of C-N bond cleavage in 1 were also performed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1007/s11426-014-5117-8 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39088]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Chu JX,Zhou QH,Li YX,et al. Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation[J]. Sci. China-Chem.,2014,57(8):1098-1105. |
| APA | 楚甲祥,周庆海,李玉学,冷雪冰,&陈耀峰.(2014).Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation.Sci. China-Chem.,57(8),1098-1105. |
| MLA | 楚甲祥,et al."Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation".Sci. China-Chem. 57.8(2014):1098-1105. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。