Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction
文献类型：期刊论文
| 作者 | Wu SY(吴生英)1; Tang J(唐俊)1; Han JW(韩建伟)1; Mao D(毛丹)1; Liu X(刘欣)1; Gao S(高省)1; Yu JJ(余建军)1; Wang LM(王利民)1 |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2014 |
| 卷号 | 70期号:35页码:5986-5992 |
| 其他题名 | 设计合成新的salen配体及其钴和镱络合物: 作为催化剂催化不对称henry反应, 并致使其产物的不对称反转效应 |
| 通讯作者 | 韩建伟 ; 王利民 |
| 英文摘要 | Reversal of enantioselectivity in asymmetric Henry reactions was achieved with novel chiral C-2-symmetric salen ligands bearing morpholine moieties by changing the Lewis acid center from Co(II) to Yb(III). The possible transition state models were supported by mass spectrometry experiments. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tet.2014.05.085 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39090]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.华东理工大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Wu SY,Tang J,Han JW,et al. Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction[J]. Tetrahedron,2014,70(35):5986-5992. |
| APA | 吴生英.,唐俊.,韩建伟.,毛丹.,刘欣.,...&王利民.(2014).Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction.Tetrahedron,70(35),5986-5992. |
| MLA | 吴生英,et al."Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction".Tetrahedron 70.35(2014):5986-5992. |
入库方式： OAI收割
来源：上海有机化学研究所
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