(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents
文献类型：期刊论文
| 作者 | Zhang HZ(张河中); 欧阳振武; Liu YS(刘月盛); Zhang Q(张强); Wang L(王磊); Deng L(邓亮) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:32页码:8432-8436 |
| 其他题名 | 氮杂环卡宾、硅二烯支撑的零价铁化合物: 一类新型的低配位零价铁试剂 |
| 通讯作者 | 邓亮 |
| 英文摘要 | The combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of unprecedented low-coordinate iron(0) alkene compounds [LnFe(eta(2) : eta(2)-dvtms)] (L=N-heterocyclic carbene (NHC) or cyclic (alkyl)(amino) carbene (CAAC), n=1 or 2) from the reactions of FeCl2 with alkali-metal reducing agents, free aminocarbene ligands, and dvtms. The iron(0) species deliver their {LnFe0} fragments to perform redox reactions with Ph2SiH2, S-8, Se, and DippN(3), furnishing novel aminocarbene-supported iron(IV) silylene, all-ferrous iron-sulfur/selenium cubanes, and bis(imido) iron(IV) compounds. These conversions demonstrate the potential synthetic utility of the carbene-supported iron(0) complexes as a valuable class of low-coordinate iron(0) reagents. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201404677 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39092]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Zhang HZ,欧阳振武,Liu YS,et al. (Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents[J]. Angew. Chem.-Int. Edit.,2014,53(32):8432-8436. |
| APA | 张河中,欧阳振武,刘月盛,张强,王磊,&邓亮.(2014).(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents.Angew. Chem.-Int. Edit.,53(32),8432-8436. |
| MLA | 张河中,et al."(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents".Angew. Chem.-Int. Edit. 53.32(2014):8432-8436. |
入库方式： OAI收割
来源：上海有机化学研究所
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