Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex
文献类型：期刊论文
| 作者 | Wang W(王薇)1; Lv YD(吕英东)1; Gou XF(苟小锋)1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1 |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2014 |
| 卷号 | 32期号:8页码:752-756 |
| 其他题名 | 钪膦宾配合物对Pinacolborane 和 Catecholborane 的B-O断裂 |
| 通讯作者 | 苟小锋 ; 陈耀峰 |
| 英文摘要 | Reactions of bis-scandium bridged phosphinidene complex, [LSc(mu-PAr)](2) (L=MeC(NDIPP)CHC(Me)(NCH2CH2N(Pr-i)(2)), DIPP = 2,6-(Pr-i)(2)C6H3; Ar = 2,6-Me2C6H3) (1), with pinacolborane, catecholborane, and 9-borabicyclo[3.3.1]nonane (9-BBN) are reported. Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate (2) and catecholate (3), showing B-O bond cleavage. These two scandium complexes contain an unusual [P(Ar)B(H)P(Ar)](2-) dianion, which displays mu-eta(2)eta(2) coordination model. On the other hand, reaction of complex 1 with 9-BBN affords the B-H bond cleavage product, 1,3-diphospha-2,4-diboracyclobutane (4). |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.201400150 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39109]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.西北大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Wang W,Lv YD,Gou XF,et al. Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex[J]. Chin. J. Chem.,2014,32(8):752-756. |
| APA | 王薇,吕英东,苟小锋,冷雪冰,&陈耀峰.(2014).Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex.Chin. J. Chem.,32(8),752-756. |
| MLA | 王薇,et al."Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex".Chin. J. Chem. 32.8(2014):752-756. |
入库方式： OAI收割
来源：上海有机化学研究所
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