Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes
文献类型：期刊论文
| 作者 | Mo ZB(莫贞波); Xiao J(肖洁); Gao YF(高亚飞); Deng L(邓亮) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2014 |
| 卷号 | 136期号:50页码:17414-17417 |
| 其他题名 | 三配位一价钴烷基硅基络合物催化的炔烃的区域选择性、立体选择性硅氢化反应 |
| 通讯作者 | 邓亮 |
| 英文摘要 | A three-coordinate cobalt(I) complex exhibits high catalytic efficiency and selectivity as well as good functional group compatibility in alkyne hydrosilylation. [Co(IAd)(PPh3)(CH2TMS)] (1) (IAd = 1,3-diadamantylimidazol-2-ylidene) facilitates regio- and stereoselective hydrosilylation of terminal, symmetrical internal, and trimethylsilyl-substituted unsymmetrical internal alkynes to produce single hydrosilylation products in the forms of beta-(E)-silylalkenes, (E)-silylalkenes, and (Z)-alpha,alpha-disilylalkenes, respectively, in high yields. The comparable catalytic efficiency and selectivity of the Co(I) silyl complex [Co(IAd)(PPh3)(SiHPh2)] that was prepared from the reaction of 1 with H2SiPh2, and the isolation of an alkyne Co(I) complex [Co(IAd)(eta(2)-PhC=CPh)(CH2TMS)] from the reaction of 1 with the acetylene, point out a modified Chalk-Harrod catalytic cycle for these hydrosilylation reactions. The high selectivity is thought to be governed by steric factors. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja510924v |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39138]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Mo ZB,Xiao J,Gao YF,et al. Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes[J]. J. Am. Chem. Soc.,2014,136(50):17414-17417. |
| APA | 莫贞波,肖洁,高亚飞,&邓亮.(2014).Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes.J. Am. Chem. Soc.,136(50),17414-17417. |
| MLA | 莫贞波,et al."Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes".J. Am. Chem. Soc. 136.50(2014):17414-17417. |
入库方式： OAI收割
来源：上海有机化学研究所
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