Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts
文献类型:期刊论文
作者 | Huang YM(黄有铭); Zheng CW(郑昌武); Chai Z(柴卓); Zhao G(赵刚) |
刊名 | Adv. Synth. Catal.
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出版日期 | 2014 |
卷号 | 356期号:2-3页码:579-583 |
其他题名 | 通过杂原子迈克尔-迈克尔加成反应合成螺[苯并二氢吡喃/四氢噻酚3,3'-氧化吲哚]构架: 双官能催化剂控制对映选择性 |
通讯作者 | 赵刚 |
英文摘要 | An efficient method for the construction of chiral spirooxindole-chroman and spirooxindole-tetrahydrothiophene scaffolds with three consecutive chiral centers including an all-carbon quaternary spirocenter has been developed. This method features an asymmetric thia/oxa-Michael-Michael cascade sequence in a single operation in the presence of chiral tertiary amine-thioureas as the catalysts, providing the desired products in good chemical yields and optical purities. |
学科主题 | 物理有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/adsc.201300833 |
语种 | 英语 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39156] ![]() |
专题 | 上海有机化学研究所_上海有机化学研究所 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Huang YM,Zheng CW,Chai Z,et al. Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts[J]. Adv. Synth. Catal.,2014,356(2-3):579-583. |
APA | 黄有铭,郑昌武,柴卓,&赵刚.(2014).Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts.Adv. Synth. Catal.,356(2-3),579-583. |
MLA | 黄有铭,et al."Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts".Adv. Synth. Catal. 356.2-3(2014):579-583. |
入库方式: OAI收割
来源:上海有机化学研究所
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