Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex
文献类型：期刊论文
| 作者 | Liu H(刘欢)1; Jiang GD(姜广德)1; Pan XX(潘希险)1; Wan XL(万晓龙)1; Lai YS(赖宜生)1; Ma DW(马大为)1; Xie WQ(谢卫青)1 |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:7页码:1908-1911 |
| 其他题名 | 色醇的不对称溴环化反应: DABCO-衍生的溴复合物的意外加速效应 |
| 通讯作者 | 赖宜生 ; 马大为 ; 谢卫青 |
| 英文摘要 | Highly asymmetric bromocyclization of tryptophol by using chiral anionic phase-transfer catalyst and DABCO-derived brominating reagent is described. Optimization of the reaction conditions revealed that the reaction rate was accelerated together with improvement of enantioselectivity by addition of catalytic DABCO-derived brominating reagent. From tryptophol, 3-bromofuroindoline could be directly obtained in excellent enantioselectivities by employing this novel methodology. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ol5004109 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39158]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 作者单位 | 1.中国药科大学 2.上海大学 3.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Liu H,Jiang GD,Pan XX,et al. Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex[J]. Org. Lett.,2014,16(7):1908-1911. |
| APA | 刘欢.,姜广德.,潘希险.,万晓龙.,赖宜生.,...&谢卫青.(2014).Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex.Org. Lett.,16(7),1908-1911. |
| MLA | 刘欢,et al."Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex".Org. Lett. 16.7(2014):1908-1911. |
入库方式： OAI收割
来源：上海有机化学研究所
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