Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning
文献类型：期刊论文
| 作者 | Zhao FG(赵福刚)1; Zhao G(赵刚)1; Liu XH(刘新华)1; Ge CW(葛从伍)1; Wang JT(王金土)1; Li BL(李柏力)1; Wang QG(王启刚)1; Li WS(李维实)1; Chen QY(陈庆云)1 |
| 刊名 | J. Mater. Chem. A
 |
| 出版日期 | 2014 |
| 卷号 | 2期号:23页码:8782-8789 |
| 其他题名 | 氟化石墨烯: 便利的溶液合成法和氟含量对性能的调控 |
| 通讯作者 | 王启刚 ; 李维实 ; 陈庆云 |
| 英文摘要 | Fluorinated graphene is one of the most important two-dimensional carbon nanomaterials derived from graphene, and possesses specific and outstanding properties. However, it lacks a cost-effective and large-scale preparation method. Here, we describe a novel and facile solution approach using graphene oxide (GO) and liquid diethylaminosulfur trifluoride as starting materials under mild conditions. The chemical composition and the structure of so-prepared fluorinated graphene were characterized in detail by elemental analysis, solid state F-19 NMR, XPS, FT-IR, Raman, SEM, TEM, and AFM. These studies reveal that some oxygen-containing moieties in GO are converted into C-F bonds, while some are eliminated during the reaction. More interestingly, the fluorine-loading amount can be well tuned by simply altering the reaction medium, and has a significant impact on the optical, electronic, and conductive properties of the product. Preliminary experiments on its application as an electrode material for solid-state supercapacitors were finally presented. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c4ta00847b |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39162]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 作者单位 | 1.中科院上海有机化学研究所 2.同济大学 |
| 推荐引用方式 GB/T 7714 | Zhao FG,Zhao G,Liu XH,et al. Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning[J]. J. Mater. Chem. A,2014,2(23):8782-8789. |
| APA | 赵福刚.,赵刚.,刘新华.,葛从伍.,王金土.,...&陈庆云.(2014).Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning.J. Mater. Chem. A,2(23),8782-8789. |
| MLA | 赵福刚,et al."Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning".J. Mater. Chem. A 2.23(2014):8782-8789. |
入库方式： OAI收割
来源：上海有机化学研究所
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