Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products
文献类型：期刊论文
| 作者 | Wan CY(万春云)1; Deng J(邓军)1; Liu H(刘华)1; Bian M(卞明)1; Li A(李昂)1 |
| 刊名 | Sci. China-Chem.
 |
| 出版日期 | 2014 |
| 卷号 | 57期号:7页码:926-929 |
| 其他题名 | Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products |
| 通讯作者 | 李昂 |
| 英文摘要 | The Diels-Alder (D-A) reaction is one of the most powerful reactions in organic synthesis. The intermolecular D-A reaction attracts much less attentions than its intramolecular counterpart in natural product synthesis, possibly due to the issues of reactivity and selectivity. In the past decade, the intermolecular D-A reaction has been increasingly utilized in the total synthesis of structurally complex natural products. In this article, we present a few examples for the elegant applications of the intermolecular D-A reaction that are inspired by biosynthetic hypotheses of the target natural products. These examples demonstrate that D-A reaction is not only useful for preparing building blocks but also powerful for coupling structurally complicated and sterically demanding segments in a highly chemo- and stereo-controlled fashion, which may inspire further developments of intermolecular D-A reaction from both strategy and methodology perspectives. |
| 学科主题 | 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1007/s11426-014-5144-5 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38947]  |
| 专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
| 作者单位 | 1.江西中医药大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Wan CY,Deng J,Liu H,et al. Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products[J]. Sci. China-Chem.,2014,57(7):926-929. |
| APA | 万春云,邓军,刘华,卞明,&李昂.(2014).Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products.Sci. China-Chem.,57(7),926-929. |
| MLA | 万春云,et al."Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products".Sci. China-Chem. 57.7(2014):926-929. |
入库方式： OAI收割
来源：上海有机化学研究所
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