Total Synthesis of Taiwaniadducts B, C, and D
文献类型:期刊论文
作者 | Deng J(邓军); Zhou SP(周述鹏); Zhang WH(张纹豪); Li J(李健); Li RF(李若凡); Li A(李昂) |
刊名 | J. Am. Chem. Soc.
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出版日期 | 2014 |
卷号 | 136期号:23页码:8185-8188 |
其他题名 | Total Synthesis of Taiwaniadducts B, C, and D |
通讯作者 | 李昂 |
英文摘要 | The first total syntheses of taiwaniadducts B, C, and D have been accomplished. Two diterpenoid segments were prepared with high enantiopurity, both through Ir-catalyzed asymmetric polyene cyclization. A sterically demanding intermolecular Diels-Alder reaction promoted by Er(fod)(3) assembled the scaffold of taiwaniadducts B and C. A carbonyl-ene cyclization forged the cage motif of taiwaniadduct D at a late stage, providing over 200 mg of this compound. |
学科主题 | 生命有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ja503972p |
语种 | 英语 |
源URL | [http://ir.sioc.ac.cn/handle/331003/38948] ![]() |
专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Deng J,Zhou SP,Zhang WH,et al. Total Synthesis of Taiwaniadducts B, C, and D[J]. J. Am. Chem. Soc.,2014,136(23):8185-8188. |
APA | 邓军,周述鹏,张纹豪,李健,李若凡,&李昂.(2014).Total Synthesis of Taiwaniadducts B, C, and D.J. Am. Chem. Soc.,136(23),8185-8188. |
MLA | 邓军,et al."Total Synthesis of Taiwaniadducts B, C, and D".J. Am. Chem. Soc. 136.23(2014):8185-8188. |
入库方式: OAI收割
来源:上海有机化学研究所
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