Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center
文献类型:期刊论文
| 作者 | Chen JH(陈锦浩)1; Cai YP(蔡跃鹏)1; Zhao G(赵刚)1 |
| 刊名 | Adv. Synth. Catal.
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| 出版日期 | 2014 |
| 卷号 | 356期号:2-3页码:359-363 |
| 其他题名 | 氮-乙酰基氨基膦催化氧化吲哚对联烯酸酯不对称加成: 构筑含季碳中心的官能化的氧化吲哚 |
| 通讯作者 | 蔡跃鹏 ; 赵刚 |
| 英文摘要 | A novel reaction between ethyl allenoate and oxindoles that enables the asymmetric synthesis of 3,3-bisubstituted oxindoles with our previously established bifunctional N-acyl aminophosphine catalysts is reported. These products bearing a chiral quaternary carbon center at the C-3 position of the oxindoles may have potential significance in the synthesis of related structures. The best performance of these processes provides adducts with 92% yield and 94% ee. |
| 学科主题 | 天然产物有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/adsc.201300695 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38972] ![]() |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 作者单位 | 1.华南师范大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Chen JH,Cai YP,Zhao G. Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center[J]. Adv. Synth. Catal.,2014,356(2-3):359-363. |
| APA | 陈锦浩,蔡跃鹏,&赵刚.(2014).Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center.Adv. Synth. Catal.,356(2-3),359-363. |
| MLA | 陈锦浩,et al."Asymmetric Michael Addition of Oxindoles to Allenoate Catalyzed by N-Acyl Aminophosphine: Construction of Functionalized Oxindoles with Quaternary Stereogenic Center".Adv. Synth. Catal. 356.2-3(2014):359-363. |
入库方式: OAI收割
来源:上海有机化学研究所
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