Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates
文献类型：期刊论文
| 作者 | Ji YL(季云龙)1; Lin JH(林锦鸿)1; Xiao JC(肖吉昌)1; Gu YC(顾玉诚)1 |
| 刊名 | Eur. J. Org. Chem.
 |
| 出版日期 | 2014 |
| 期号 | 35页码:7948-7954 |
| 其他题名 | Au(I)/Cu(I)催化下醋酸炔丙酯的串联1,3-酰氧基迁移/三氟甲基化 |
| 通讯作者 | 林锦鸿 ; 肖吉昌 |
| 英文摘要 | Au-I/Cu-I-co-catalyzed tandem 1,3-acyloxy migration/trifluoromethylation reaction of propargyl esters to give -trifluoromethyl enones in moderate yields and with excellent stereoselectivity is described. It is proposed that the reaction proceeds through the 1,3-acyloxy migration of the propargyl esters catalyzed by Au-I to produce an allenic intermediate, followed by its trifluoromethylation to give the final product. |
| 学科主题 | 氟化学; 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/ejoc.201403115 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38830]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所 2.英国先正达公司 |
| 推荐引用方式 GB/T 7714 | Ji YL,Lin JH,Xiao JC,et al. Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates[J]. Eur. J. Org. Chem.,2014(35):7948-7954. |
| APA | 季云龙,林锦鸿,肖吉昌,&顾玉诚.(2014).Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates.Eur. J. Org. Chem.(35),7948-7954. |
| MLA | 季云龙,et al."Stereoselective Synthesis of alpha-Trifluoromethyl Enones by Au-I/Cu-I-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates".Eur. J. Org. Chem. .35(2014):7948-7954. |
入库方式： OAI收割
来源：上海有机化学研究所
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