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N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent
文献类型：期刊论文
| 作者 | Xu CF(徐春发); Ma BQ(马冰清); Shen QL(沈其龙) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:35页码:9316-9320 |
| 其他题名 | 糖精衍生的三氟甲硫基试剂: 一种易合成、稳定、适用范围广的亲电三氟甲硫基试剂 |
| 通讯作者 | 沈其龙 |
| 英文摘要 | A new, electrophilic trifluoromethylthiolating reagent, N-trifluoromethylthiosaccharin, was developed and can be synthesized in two steps from saccharin within 30 minutes. N-trifluoromethylthiosaccharin is a powerful trifluoromethylthiolating reagent and allows the trifluoromethylthiolation of a variety of nucleophiles such as alcohols, amines, thiols, electron-rich arenes, aldehydes, ketones, acyclic beta-ketoesters, and alkynes under mild reaction conditions. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201403983 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38856]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Xu CF,Ma BQ,Shen QL. N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent[J]. Angew. Chem.-Int. Edit.,2014,53(35):9316-9320. |
| APA | 徐春发,马冰清,&沈其龙.(2014).N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent.Angew. Chem.-Int. Edit.,53(35),9316-9320. |
| MLA | 徐春发,et al."N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent".Angew. Chem.-Int. Edit. 53.35(2014):9316-9320. |
入库方式： OAI收割
来源：上海有机化学研究所
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