Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium
文献类型：期刊论文
| 作者 | Min QQ(闵巧桥); Yin ZS(尹增升); Feng Z(冯璋); Guo WH(郭文豪); Zhang XG(张新刚) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2014 |
| 卷号 | 136期号:4页码:1230-1233 |
| 其他题名 | 钯催化下溴二氟丙烯对有机硼试剂的高选择性偕二氟烯丙基化 |
| 通讯作者 | 张新刚 |
| 英文摘要 | A first example of Pd-catalyzed gem-difluoroallylation of organoborons using 3-bromo-3,3-difluoropropene (BDFP) in high efficiency with high alpha/gamma-substitution regioselectivity has been developed. The reaction can also be extended to substituted BDFPs and has advantages of low catalyst loading (0.8 to 0.01 mol %), broad substrate scope, and excellent functional group compatibility, thus providing a facile route for practical application in drug discovery and development. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja4114825 |
| 语种 | 英语 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/38875]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Min QQ,Yin ZS,Feng Z,et al. Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium[J]. J. Am. Chem. Soc.,2014,136(4):1230-1233. |
| APA | 闵巧桥,尹增升,冯璋,郭文豪,&张新刚.(2014).Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium.J. Am. Chem. Soc.,136(4),1230-1233. |
| MLA | 闵巧桥,et al."Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium".J. Am. Chem. Soc. 136.4(2014):1230-1233. |
入库方式： OAI收割
来源：上海有机化学研究所
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