Immobilization of highly active Pd nano-catalysts on functionalized mesoporous silica supports using mercapto groups as anchoring sites and their catalytic performance for phenol hydrogenation
文献类型：期刊论文
| 作者 | Zhang, Jiaxi1; Huang, Gaowei1; Zhang, Cheng1,2; He, Qunhua2; Huang, Chao1; Yang, Xu3; Song, Huiyu1; Liang, Zhenxing1; Du, Li1,4; Liao, Shijun1,4 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2013-08-01 |
| 卷号 | 34期号:8页码:1519-1526 |
| 关键词 | Mesoporous silica Mercapto group functionalization Palladium Anchoring Supported catalyst Phenol hydrogenation |
| 英文摘要 | highly active and highly dispersed pd-loaded nano-catalysts using mercapto group (-sh) functionalized mesoporous silica supports, namely, pd-sh-mcm-41 and pd-sh-sba-15, were prepared using an impregnation-reduction approach. the surface -sh groups are believed to facilitate the high distribution and immobilization of the pd nanoparticles within the silica supports through an anchoring interaction. the catalysts featured long-range ordered structures, uniform pore size, high surface area, and highly dispersed pd nanoparticles as characterized by x-ray diffraction, n-2 adsorption-desorption, and transmission electron microscopy. the catalysts showed activity five times higher than that of commercial pd/c catalyst and three times higher than those of pd/mcm-41 and pd/sba-15 catalysts. within 1 h of reaction at 80 degrees c and 1.0 mpa, the conversion of phenol attained was greater than 99%, and the selectivity for cyclohexanone was 98%. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | cyclohexanone ; sba-15 ; nanospheres ; adsorption ; lipase |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323239600007 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10040]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 2.Guangdong Environm Monitoring Ctr, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 4.S China Univ Technol, Sch Chem & Chem Engn, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jiaxi,Huang, Gaowei,Zhang, Cheng,et al. Immobilization of highly active Pd nano-catalysts on functionalized mesoporous silica supports using mercapto groups as anchoring sites and their catalytic performance for phenol hydrogenation[J]. chinese journal of catalysis,2013,34(8):1519-1526. |
| APA | Zhang, Jiaxi.,Huang, Gaowei.,Zhang, Cheng.,He, Qunhua.,Huang, Chao.,...&Liao, Shijun.(2013).Immobilization of highly active Pd nano-catalysts on functionalized mesoporous silica supports using mercapto groups as anchoring sites and their catalytic performance for phenol hydrogenation.chinese journal of catalysis,34(8),1519-1526. |
| MLA | Zhang, Jiaxi,et al."Immobilization of highly active Pd nano-catalysts on functionalized mesoporous silica supports using mercapto groups as anchoring sites and their catalytic performance for phenol hydrogenation".chinese journal of catalysis 34.8(2013):1519-1526. |
入库方式： OAI收割
来源：广州能源研究所
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