Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts
文献类型：期刊论文
| 作者 | Yu Yu-Xiao1,2; Zhang Xing-Hua1,2 ; Wang Tie-Jun1; Xu Ying1; Ma Long-Long1; Zhang Qi1; Zhang Li-Min3
|
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2013-09-10 |
| 卷号 | 34期号:9页码:2178-2183 |
| 关键词 | Bio-oil Ni-B catalyst Aqueous-phase reforming Saturated alcohol |
| 英文摘要 | ni-b amorphous catalysts were prepared by chemical reduction of nickel chloride with potassium borohydride aqueous solution and characterized by x-ray diffraction(xrd), brunauer-emmett-tetter(bet), scanning electron microscopy (sem), transmission electron microscopy (tem), inductively coupled plasma (icp) techniques. the catalytic performances of model compounds and bio-oil to produce saturated alcohols were evaluated in a semi-batch reactor. the results showed that the conversion of model compounds(acetone, furfural and phenol) and the selectivity of saturated alcohols reached 99.99% and 90.00% at 110 degrees c, 4.0 mpa(initial pressure). under the conditions of 150 degrees c and 4.0 mpa, the yield of saturated alcohols reached 47.54%. high temperature of above 150 degrees c resulted in the transformation of amorphous phase to form crystal, which was attributed to the low catalytic activity. this work provides a new alternative for the production of saturated alcohols from bio-oil. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | alloy catalyst ; pyrolysis oil ; hydrodeoxygenation ; biomass ; hydrotreatment ; phenol ; la |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000328926400026 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10047]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu Yu-Xiao,Zhang Xing-Hua,Wang Tie-Jun,et al. Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts[J]. chemical journal of chinese universities-chinese,2013,34(9):2178-2183. |
| APA | Yu Yu-Xiao.,Zhang Xing-Hua.,Wang Tie-Jun.,Xu Ying.,Ma Long-Long.,...&Zhang Li-Min.(2013).Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts.chemical journal of chinese universities-chinese,34(9),2178-2183. |
| MLA | Yu Yu-Xiao,et al."Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts".chemical journal of chinese universities-chinese 34.9(2013):2178-2183. |
入库方式： OAI收割
来源：广州能源研究所
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