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Hydrotreatment of bio-oil over Ni-based catalyst

文献类型:期刊论文

作者Zhang, Xinghua1,2; Wang, Tiejun1; Ma, Longlong1; Zhang, Qi1; Jiang, Ting1,2
刊名bioresource technology
出版日期2013
卷号127页码:306-311
关键词Bio-oil Phenol Ni-based catalysts Hydrodeoxygenation (HDO) Upgrading
英文摘要inexpensive non-sulfided ni-based catalysts were evaluated for hydrotreatments using phenol as model compound. hzsm-5, a zeolite with different ratio of si/al and gamma-al2o3 were impregnated with ni(no3)(2)center dot 6h(2)o and calcined at 450 degrees c. conversion rates and product distribution for treatment of phenol at 160-240 degrees c in the presence of catalysts with nickel loads of 6, 10, 14 and 17 wt.% were determined. phenol conversion was highest (91.8%) at 240 degrees c in the presence of hzsm-5(si/al = 38) loaded with 10% ni. when hydrotreatment was carried out with bio-oil obtained from pyrolysis of pine sawdust under the optimal conditions determined for phenol, the ph of bio-oil increased from 2.27 to 4.07, and the hydrogen content increased from 6.28 to 7.01 wt.%. the decrease in acidity is desirable for the use of upgraded bio-oil. (c) 2012 published by elsevier ltd.
WOS标题词science & technology ; life sciences & biomedicine ; technology
类目[WOS]agricultural engineering ; biotechnology & applied microbiology ; energy & fuels
研究领域[WOS]agriculture ; biotechnology & applied microbiology ; energy & fuels
关键词[WOS]pyrolysis oil ; liquid fuel ; hydrodeoxygenation ; biomass ; conversion ; hydrogen ; fraction ; lignin ; hzsm-5 ; pd
收录类别SCI
语种英语
WOS记录号WOS:000312926400042
源URL[http://ir.giec.ac.cn/handle/344007/10078]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,et al. Hydrotreatment of bio-oil over Ni-based catalyst[J]. bioresource technology,2013,127:306-311.
APA Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,Zhang, Qi,&Jiang, Ting.(2013).Hydrotreatment of bio-oil over Ni-based catalyst.bioresource technology,127,306-311.
MLA Zhang, Xinghua,et al."Hydrotreatment of bio-oil over Ni-based catalyst".bioresource technology 127(2013):306-311.

入库方式: OAI收割

来源:广州能源研究所

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