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Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts

文献类型:期刊论文

作者Zhang, Xinghua1,2; Zhang, Qi1; Wang, Tiejun1; Ma, Longlong1; Yu, Yuxiao1,2; Chen, Lungang1
刊名bioresource technology
出版日期2013-04-01
卷号134页码:73-80
关键词SiO2-ZrO2 Phenolic compounds Hydrodeoxygenation (HDO) Hydrocarbon
英文摘要inexpensive non-sulfided ni-based catalysts were evaluated for hydrodeoxygenation (hdo) using guaiacol as model compound. sio2-zro2 (sz), a complex oxide synthesized by precipitation method with different ratio of si/zr, was impregnated with ni(no3)(2)center dot 6h(2)o and calcined at 500 degrees c. conversion rates and product distribution for guaiacol hdo at 200-340 degrees c were determined. guaiacol conversion reached the maximum at 300 degrees c in the presence of ni/sz-3. when hdo reaction was carried out with real lignin-derived phenolic compounds under the optimal conditions determined for guaiacol, the total yield of hydrocarbons was 62.81%. these hydrocarbons were comprised of cyclohexane, alkyl-substituted cyclohexane and alkyl-substituted benzene. they have high octane number, would be the most desirable components for fungible liquid transportation fuel. (c) 2013 elsevier ltd. all rights reserved.
WOS标题词science & technology ; life sciences & biomedicine ; technology
类目[WOS]agricultural engineering ; biotechnology & applied microbiology ; energy & fuels
研究领域[WOS]agriculture ; biotechnology & applied microbiology ; energy & fuels
关键词[WOS]noble-metal catalysts ; bio-oil ; biomass ; hydrogenolysis ; conversion ; pyrolysis ; zirconia ; guaiacol ; sulfide ; alkanes
收录类别SCI
语种英语
WOS记录号WOS:000328512800002
源URL[http://ir.giec.ac.cn/handle/344007/10084]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,et al. Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts[J]. bioresource technology,2013,134:73-80.
APA Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,Ma, Longlong,Yu, Yuxiao,&Chen, Lungang.(2013).Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts.bioresource technology,134,73-80.
MLA Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts".bioresource technology 134(2013):73-80.

入库方式: OAI收割

来源:广州能源研究所

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