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Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts
文献类型:期刊论文
作者 | Zhang, Xinghua1,2![]() ![]() ![]() ![]() |
刊名 | bioresource technology
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出版日期 | 2013-04-01 |
卷号 | 134页码:73-80 |
关键词 | SiO2-ZrO2 Phenolic compounds Hydrodeoxygenation (HDO) Hydrocarbon |
英文摘要 | inexpensive non-sulfided ni-based catalysts were evaluated for hydrodeoxygenation (hdo) using guaiacol as model compound. sio2-zro2 (sz), a complex oxide synthesized by precipitation method with different ratio of si/zr, was impregnated with ni(no3)(2)center dot 6h(2)o and calcined at 500 degrees c. conversion rates and product distribution for guaiacol hdo at 200-340 degrees c were determined. guaiacol conversion reached the maximum at 300 degrees c in the presence of ni/sz-3. when hdo reaction was carried out with real lignin-derived phenolic compounds under the optimal conditions determined for guaiacol, the total yield of hydrocarbons was 62.81%. these hydrocarbons were comprised of cyclohexane, alkyl-substituted cyclohexane and alkyl-substituted benzene. they have high octane number, would be the most desirable components for fungible liquid transportation fuel. (c) 2013 elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
关键词[WOS] | noble-metal catalysts ; bio-oil ; biomass ; hydrogenolysis ; conversion ; pyrolysis ; zirconia ; guaiacol ; sulfide ; alkanes |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000328512800002 |
源URL | [http://ir.giec.ac.cn/handle/344007/10084] ![]() |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,et al. Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts[J]. bioresource technology,2013,134:73-80. |
APA | Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,Ma, Longlong,Yu, Yuxiao,&Chen, Lungang.(2013).Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts.bioresource technology,134,73-80. |
MLA | Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts".bioresource technology 134(2013):73-80. |
入库方式: OAI收割
来源:广州能源研究所
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