Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media
文献类型：期刊论文
| 作者 | Chen, Jinzhu1; Huang, Jing1; Chen, Limin2; Ma, Longlong1; Wang, Tiejun1; Zakai, Uzma I.1 |
| 刊名 | chemcatchem
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 5期号:6页码:1598-1605 |
| 关键词 | biomass heterogeneous catalysis hydrodeoxygenation ionic liquids phenol |
| 英文摘要 | using phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer a-stabilized nanocatalysts and the mineral acid h3po4. the developed ru/a-h3po4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. mercury poisoning experiments revealed that the insitu generated ru nanoparticles are true a heterogeneous catalyst for hydrogenation. the catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of ru>rh>pt >> pd. our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. the research highlights an efficient catalyst system of transforming phenols into alkanes. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | fast pyrolysis processes ; bio-oils ; biomass ; catalysts ; alkanes ; hydrogenation ; complexes ; metal |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000319680800049 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10101]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. chemcatchem,2013,5(6):1598-1605. |
| APA | Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.chemcatchem,5(6),1598-1605. |
| MLA | Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".chemcatchem 5.6(2013):1598-1605. |
入库方式： OAI收割
来源：广州能源研究所
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