Directional synthesis of ethylbenzene through catalytic transformation of lignin
文献类型：期刊论文
| 作者 | Fan, Minghui1; Jiang, Peiwen1; Bi, Peiyan1; Deng, Shumei1; Yan, Lifeng1; Zhai, Qi1; Wang, Tiejun2; Li, Quanxin1 |
| 刊名 | bioresource technology
 |
| 出版日期 | 2013-09-01 |
| 卷号 | 143页码:59-67 |
| 关键词 | Lignin Ethylbenzene Aromatic monomer Depolymerization Alkylation |
| 英文摘要 | transformation of lignin to ethylbenzene can provide an important bulk raw material for the petrochemical industry. this work explored the production of ethylbenzene from lignin through the directional catalytic depolymerization of lignin into the aromatic monomers followed by the selective alkylation of the aromatic monomers. for the first step, the aromatics selectivity of benzene derived from the catalytic depolymerization of lignin reached about 90.2 c-mol% over the composite catalyst of re-y/hzsm-5 (25). for the alkylation of the aromatic monomers in the second step, the highest selectivity of ethylbenzene was about 72.3 c-mol% over the hzsm-5 (25) catalyst. the reaction pathway for the transformation of lignin to ethylbenzene was also addressed. present transformation potentially provides a useful approach for the production of the basic petrochemical material and development of high-end chemicals utilizing lignin as the abundant natural aromatic resource. (c) 2013 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
| 类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
| 研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
| 关键词[WOS] | light olefins ; bio-oil ; alkylation ; benzene ; zeolite ; conversion ; depolymerization ; ethylation ; aromatics ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323239800009 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10116]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Anhui Key Lab Biomass Clean Energy, Dept Chem Phys, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Minghui,Jiang, Peiwen,Bi, Peiyan,et al. Directional synthesis of ethylbenzene through catalytic transformation of lignin[J]. bioresource technology,2013,143:59-67. |
| APA | Fan, Minghui.,Jiang, Peiwen.,Bi, Peiyan.,Deng, Shumei.,Yan, Lifeng.,...&Li, Quanxin.(2013).Directional synthesis of ethylbenzene through catalytic transformation of lignin.bioresource technology,143,59-67. |
| MLA | Fan, Minghui,et al."Directional synthesis of ethylbenzene through catalytic transformation of lignin".bioresource technology 143(2013):59-67. |
入库方式： OAI收割
来源：广州能源研究所
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