Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer
文献类型:期刊论文
作者 | Qiu, Minghuang; Li, Yuping![]() ![]() ![]() ![]() ![]() ![]() ![]() |
刊名 | applied energy
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出版日期 | 2012-02-01 |
卷号 | 90期号:1页码:3-10 |
关键词 | Biomass fuel gas Reforming NiO-MgO/gamma-Al2O3 cordierite monolithic catalysts Reformer |
英文摘要 | the effect of ni/mg mole ratio of ni-mgo/gamma-al2o3 cordierite monolithic catalysts on dry reforming of model biomass fuel gas(h-2/co/c2h4/ch4/co2/n-2 = 16.0/12.1/2.5/15.1/22.0/32.3, vol.%) was investigated in a lab-scale stainless steel tubular reactor. the results showed that ch4 and co2 conversions, h-2 and co yields and h-2/co ratio in the tail gas was 87.2%, 54.4%, 65.2%, 43.0%, and 1.17 respectively at 750 degrees c over the optimized mcni0.51mr0.49o (the ratio was 0.51:0.49 with 8.3 wt% nio loading amount) during 60 h of time on stream (tos). and the formation of nio-mgo solid solution structure would restrain the active ni-0 centers from agglomeration and decrease carbon deposition. cold test of the vertical-placed tubular reformers (packed by monolith of 7 mm cell spacing) indicated that the pressure drop was as low as 850 pa at 1.57 m/s of gas velocity with 330 g/m(3) fly ash added. the reforming of real biomass fuel gas (h-2/co/c2h4/ch4/co2/n-2 = 10.2/16.8/0.5/6.4/15.2/51.0, vol.%, from air gasification of 200-250 kg/h pine sawdust in the pilot plant) in the multi-tube reformer packed with mcp (larger in size than mcni0.51mg0.49o) exhibits the pressure drop of less than 700 pa, ch4 and co2 conversions of about 84% and 38.5% and the decrease of tar content from 4.8-5.3 g/m(3) to 0.12-0.14 g/m(3) during 60 h tos at 670 degrees c. the characterization of the spent catalysts by tg, xrd and icp-aes proved the anti-sintering and anti-carbon deposition properties of nio-mgo solid solution monolithic catalyst. (c) 2011 elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; technology |
类目[WOS] | energy & fuels ; engineering, chemical |
研究领域[WOS] | energy & fuels ; engineering |
关键词[WOS] | ni/mgo catalysts ; fluidized-beds ; ni catalysts ; gasification ; methane ; oxidation ; syngas ; model |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS记录号 | WOS:000297426100002 |
源URL | [http://ir.giec.ac.cn/handle/344007/10539] ![]() |
专题 | 中国科学院广州能源研究所 |
作者单位 | Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Qiu, Minghuang,Li, Yuping,Wang, Tiejun,et al. Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer[J]. applied energy,2012,90(1):3-10. |
APA | Qiu, Minghuang.,Li, Yuping.,Wang, Tiejun.,Zhang, Qing.,Wang, Chenguang.,...&Li, Kai.(2012).Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer.applied energy,90(1),3-10. |
MLA | Qiu, Minghuang,et al."Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer".applied energy 90.1(2012):3-10. |
入库方式: OAI收割
来源:广州能源研究所
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