中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer

文献类型:期刊论文

作者Qiu, Minghuang; Li, Yuping; Wang, Tiejun; Zhang, Qing; Wang, Chenguang; Zhang, Xinghua; Wu, Chuangzhi; Ma, Longlong; Li, Kai
刊名applied energy
出版日期2012-02-01
卷号90期号:1页码:3-10
关键词Biomass fuel gas Reforming NiO-MgO/gamma-Al2O3 cordierite monolithic catalysts Reformer
英文摘要

the effect of ni/mg mole ratio of ni-mgo/gamma-al2o3 cordierite monolithic catalysts on dry reforming of model biomass fuel gas(h-2/co/c2h4/ch4/co2/n-2 = 16.0/12.1/2.5/15.1/22.0/32.3, vol.%) was investigated in a lab-scale stainless steel tubular reactor. the results showed that ch4 and co2 conversions, h-2 and co yields and h-2/co ratio in the tail gas was 87.2%, 54.4%, 65.2%, 43.0%, and 1.17 respectively at 750 degrees c over the optimized mcni0.51mr0.49o (the ratio was 0.51:0.49 with 8.3 wt% nio loading amount) during 60 h of time on stream (tos). and the formation of nio-mgo solid solution structure would restrain the active ni-0 centers from agglomeration and decrease carbon deposition. cold test of the vertical-placed tubular reformers (packed by monolith of 7 mm cell spacing) indicated that the pressure drop was as low as 850 pa at 1.57 m/s of gas velocity with 330 g/m(3) fly ash added. the reforming of real biomass fuel gas (h-2/co/c2h4/ch4/co2/n-2 = 10.2/16.8/0.5/6.4/15.2/51.0, vol.%, from air gasification of 200-250 kg/h pine sawdust in the pilot plant) in the multi-tube reformer packed with mcp (larger in size than mcni0.51mg0.49o) exhibits the pressure drop of less than 700 pa, ch4 and co2 conversions of about 84% and 38.5% and the decrease of tar content from 4.8-5.3 g/m(3) to 0.12-0.14 g/m(3) during 60 h tos at 670 degrees c. the characterization of the spent catalysts by tg, xrd and icp-aes proved the anti-sintering and anti-carbon deposition properties of nio-mgo solid solution monolithic catalyst. (c) 2011 elsevier ltd. all rights reserved.

WOS标题词science & technology ; technology
类目[WOS]energy & fuels ; engineering, chemical
研究领域[WOS]energy & fuels ; engineering
关键词[WOS]ni/mgo catalysts ; fluidized-beds ; ni catalysts ; gasification ; methane ; oxidation ; syngas ; model
收录类别SCI ; ISTP
语种英语
WOS记录号WOS:000297426100002
源URL[http://ir.giec.ac.cn/handle/344007/10539]  
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714
Qiu, Minghuang,Li, Yuping,Wang, Tiejun,et al. Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer[J]. applied energy,2012,90(1):3-10.
APA Qiu, Minghuang.,Li, Yuping.,Wang, Tiejun.,Zhang, Qing.,Wang, Chenguang.,...&Li, Kai.(2012).Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer.applied energy,90(1),3-10.
MLA Qiu, Minghuang,et al."Upgrading biomass fuel gas by reforming over Ni-MgO/gamma-Al2O3 cordierite monolithic catalysts in the lab-scale reactor and pilot-scale multi-tube reformer".applied energy 90.1(2012):3-10.

入库方式: OAI收割

来源:广州能源研究所

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