High yield of pentane production by aqueous-phase reforming of xylitol over Ni/HZSM-5 and Ni/MCM22 catalysts
文献类型：期刊论文
| 作者 | Jiang, Ting1,2; Zhang, Qing1; Wang, Tie-Jun1; Zhang, Qi1; Ma, Long-Long1 |
| 刊名 | energy conversion and management
 |
| 出版日期 | 2012-07-01 |
| 卷号 | 59页码:58-65 |
| 关键词 | Xylitol Pentane, Ni/HZSM-5 Ni/MCM22 Aqueous-phase reforming |
| 英文摘要 | ni/hzsm-5 and ni/mcm22 catalysts with different ni loadings were prepared by impregnation method and evaluated for aqueous-phase reforming (apr) reaction of xylitol at 240 degrees c and 4 mpa. effects of ni loadings on the xylitol conversion and pentane selectivity of the catalyst was investigated. the results showed that the catalytic activities of the two ni/hzsm-5 and ni/mcm22 catalysts both increased with increasing ni loading in the range of 0-2%. and then decreased as ni loading further increased to 4%. maximum pentane yields of 91% and 95% could be obtained over 2%ni/hzsm-5 and 2%ni/mcm22, respectively. 2%ni/hzsm-5 deactivated obviously after five recycle runs, while 2%ni/mcm22 still kept excellent activity with the pentane yield of 90-95%. the catalysts with different ni loading were characterized by bet, h-2-tpr and nh3-tpd techniques and the used selected 2%ni/mcm22 and 2%ni/hzsm-5 catalyst were also characterized by xrd, ftir and tg. the characterization results revealed that 2%ni/mcm22 and 2%ni/hzsm-5 have similar amounts of ni active sites, while the 2%ni/mcm22 has larger surface area, more mesopore and less strong acid sites than the 2%ni/hzsm-5. moreover, partial dealumination and coke formation of the used 2%ni/hzsm-5 catalyst were found. all these factors resulted in the deactivation of 2%ni/hzsm-5 after five recycle runs. (c) 2012 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | thermodynamics ; energy & fuels ; mechanics ; physics, nuclear |
| 研究领域[WOS] | thermodynamics ; energy & fuels ; mechanics ; physics |
| 关键词[WOS] | temperature-programmed desorption ; oxygenated hydrocarbons ; liquid alkanes ; zeolite mcm-22 ; biomass ; conversion ; sorbitol ; hydrogen ; biorefinery ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000304513000008 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10591]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Ting,Zhang, Qing,Wang, Tie-Jun,et al. High yield of pentane production by aqueous-phase reforming of xylitol over Ni/HZSM-5 and Ni/MCM22 catalysts[J]. energy conversion and management,2012,59:58-65. |
| APA | Jiang, Ting,Zhang, Qing,Wang, Tie-Jun,Zhang, Qi,&Ma, Long-Long.(2012).High yield of pentane production by aqueous-phase reforming of xylitol over Ni/HZSM-5 and Ni/MCM22 catalysts.energy conversion and management,59,58-65. |
| MLA | Jiang, Ting,et al."High yield of pentane production by aqueous-phase reforming of xylitol over Ni/HZSM-5 and Ni/MCM22 catalysts".energy conversion and management 59(2012):58-65. |
入库方式： OAI收割
来源：广州能源研究所
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