Hydrodeoxygenation of palm oil to hydrocarbon fuels over Ni/SAPO-11 catalysts
文献类型：期刊论文
| 作者 | Liu, Qiying; Zuo, Hualiang; Zhang, Qi; Wang, Tiejun; Ma, Longlong |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-05-01 |
| 卷号 | 35期号:5页码:748-756 |
| 关键词 | Palm oil Hydrodeoxygenation Hydrocarbon Isomerization Synergistic effect |
| 英文摘要 | small particles of sapo-11 with large surface area and mesoporosity were synthesized hydrothermally. ni/sapo-11 catalysts with different ni loadings were prepared by incipient wetness impregnation, and their physicochemical properties were characterized by x-ray diffraction, scanning electron microscopy, n-2 adsorption-desorption, nh3 temperature-programmed desorption, thermogravimetric, and h-2 chemisorption. in the ni impregnation of sapo-11, the mesopores of sapo-11 accommodated the ni particles and give good dispersions, but with the partial blocking of some micropores. in the hydrodeoxygenation of palm oil, the production of liquid alkanes depends on the competition between hydrodeoxygenation and decarbonylation pathways via the corresponding carboxylic acid intermediates. the weak and medium acidity of sapo-11 and a good match of the ni and sapo-11 functions in the ni/sapo-11 catalysts decreased the cracking of primary long chain alkanes and gave a high liquid alkane yield of 70 wt% and isomerization selectivity of >80 mol%. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | hydrogenated vegetable-oils ; sulfided nimo/gamma-al2o3 ; molecular-sieves ; jatropha oil ; acid ; isomerization ; biodiesel ; esters ; deoxygenation ; conversion |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000335622300018 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10621]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Qiying,Zuo, Hualiang,Zhang, Qi,et al. Hydrodeoxygenation of palm oil to hydrocarbon fuels over Ni/SAPO-11 catalysts[J]. chinese journal of catalysis,2014,35(5):748-756. |
| APA | Liu, Qiying,Zuo, Hualiang,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2014).Hydrodeoxygenation of palm oil to hydrocarbon fuels over Ni/SAPO-11 catalysts.chinese journal of catalysis,35(5),748-756. |
| MLA | Liu, Qiying,et al."Hydrodeoxygenation of palm oil to hydrocarbon fuels over Ni/SAPO-11 catalysts".chinese journal of catalysis 35.5(2014):748-756. |
入库方式： OAI收割
来源：广州能源研究所
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