Nano-CdS confined within titanate nanotubes for efficient photocatalytic hydrogen production under visible light illumination
文献类型:期刊论文
作者 | Long, Lizhen1,2; Yu, Xiang3; Wu, Liangpeng1![]() ![]() ![]() |
刊名 | nanotechnology
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出版日期 | 2014-01-24 |
卷号 | 25期号:3 |
关键词 | CdS nanoparticles titanate nanotubes confinement effect hydrogen production quantum size effect |
英文摘要 | cds nanoparticles were confined within titanate nanotubes (tnts) by an ion-exchange reaction and a subsequent sulfurization process. prior to the ion-exchange reaction, the exterior surfaces of the tnts were modified by a silane coupling agent to make cds nanoparticles selectively deposit on the inner wall. the composites were characterized by high-resolution transmission electron microscopy, powder x-ray diffraction, inductively coupled plasma atomic emission spectrometry, n-2 adsorption-desorption and uv-vis absorption spectra. the results confirm that cds in the range of 2-3 nm in diameter are confined within the inner cavity of the tnts. cds confined within tnts shows a significant blue-shift of the absorption band edge compared with cds nanoparticles deposited on the exterior surface of tnts. also the tnts-confined cds composite exhibits enhanced photocatalytic activity and photostability for hydrogen evolution under visible light illumination due to the quantum size effect of cds as a result of the spatial confinement effect of the tnts. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | nanoscience & nanotechnology ; materials science, multidisciplinary ; physics, applied |
研究领域[WOS] | science & technology - other topics ; materials science ; physics |
关键词[WOS] | tio2 nanotubes ; cadmium-sulfide ; water ; architecture ; irradiation ; evolution ; size |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000329040400014 |
源URL | [http://ir.giec.ac.cn/handle/344007/10629] ![]() |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Jinan Univ, Analyt & Testing Ctr, Guangzhou 510632, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Long, Lizhen,Yu, Xiang,Wu, Liangpeng,et al. Nano-CdS confined within titanate nanotubes for efficient photocatalytic hydrogen production under visible light illumination[J]. nanotechnology,2014,25(3). |
APA | Long, Lizhen,Yu, Xiang,Wu, Liangpeng,Li, Juan,&Li, Xinjun.(2014).Nano-CdS confined within titanate nanotubes for efficient photocatalytic hydrogen production under visible light illumination.nanotechnology,25(3). |
MLA | Long, Lizhen,et al."Nano-CdS confined within titanate nanotubes for efficient photocatalytic hydrogen production under visible light illumination".nanotechnology 25.3(2014). |
入库方式: OAI收割
来源:广州能源研究所
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