Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts
文献类型:期刊论文
作者 | Li Yanbin1,2; Xu Ying2,3; Ma Longlong1,2,3; Zhang Qi2,3; Wang Tiejun2,3; Chen Guanyi1; Zhang Limin2 |
刊名 | chemical journal of chinese universities-chinese
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出版日期 | 2014-12-10 |
卷号 | 35期号:12页码:2654-2661 |
关键词 | In situ hydrogenation o-Cresol Nickel-based CMK-3 catalyst |
英文摘要 | in situ hydrogenation was studied by means of ni loading, temperature, initial pressure, and reaction time over ni/cmk-3 catalysts. the catalysts were characterized by x-ray diffraction(xrd), h-2 temperature programmed reduction(h-2-tpr) and n-2 adsorption-desorption isotherms. the results revealed that the optimal conditions were confirmed as follow: ni loading of 20% (mass fraction), reaction temperature of 230 degrees c, initial pressure of 0. 1 mpa, reaction time of 9 h for in situ hydrogenation. the maximum conversion of o-cresol in optimal condition was determined as 47. 56%. compared with the effect of hydrogen donor solvents, formic acid was the best of four kinds of solvents. the comparsion of cresol isomers, recyclability of ni/cmk-3 were also discussed. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | oil model compounds ; bio-oil ; platinum catalysts ; generated hydrogen ; mesoporous carbons ; pyrolysis oil ; hydrodeoxygenation ; phenol ; performance ; compound |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000347669400025 |
源URL | [http://ir.giec.ac.cn/handle/344007/10643] ![]() |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Tianjin Univ, State Key Lab Int Combust Engine, Fac Environm Sci & Engn, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Li Yanbin,Xu Ying,Ma Longlong,et al. Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts[J]. chemical journal of chinese universities-chinese,2014,35(12):2654-2661. |
APA | Li Yanbin.,Xu Ying.,Ma Longlong.,Zhang Qi.,Wang Tiejun.,...&Zhang Limin.(2014).Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts.chemical journal of chinese universities-chinese,35(12),2654-2661. |
MLA | Li Yanbin,et al."Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts".chemical journal of chinese universities-chinese 35.12(2014):2654-2661. |
入库方式: OAI收割
来源:广州能源研究所
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