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All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode

文献类型:期刊论文

作者Zhu, Zhiqiang1,2; Hong, Meiling1,2; Guo, Dongsheng1,2; Shi, Jifu3; Tao, Zhanliang1,2; Chen, Jun1,2
刊名journal of the american chemical society
出版日期2014-11-26
卷号136期号:47页码:16461-16464
英文摘要the cathode capacity of common lithium ion batteries (libs) using inorganic electrodes and liquid electrolytes must be further improved. alternatively, all-solid-state lithium batteries comprising the electrode of organic compounds can offer much higher capacity. herein, we successfully fabricated an all-solid-state lithium battery based on organic pillar[5]quinone (c35h20o10) cathode and composite polymer electrolyte (cpe). the poly(methacrylate) (pma)/poly(ethylene glycol) (peg)-liclo4-3 wt % sio2 cpe has an optimum ionic conductivity of 0.26 ms cm(-1) at room temperature. furthermore, pillar[5]quinine cathode in all-solid-state battery rendered an average operation voltage of similar to 2.6 v and a high initial capacity of 418 mah g(-1) with a stable cyclability (94.7% capacity retention after 50 cycles at 0.2c rate) through the reversible redox reactions of enolate/quinonid carbonyl groups, showing favorable prospect for the device application with high capacity.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]soggy sand electrolytes ; li-ion batteries ; energy-storage ; salt-solutions ; oxide)
收录类别SCI
语种英语
WOS记录号WOS:000345720500001
源URL[http://ir.giec.ac.cn/handle/344007/10696]  
专题中国科学院广州能源研究所
作者单位1.Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
2.Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Zhiqiang,Hong, Meiling,Guo, Dongsheng,et al. All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode[J]. journal of the american chemical society,2014,136(47):16461-16464.
APA Zhu, Zhiqiang,Hong, Meiling,Guo, Dongsheng,Shi, Jifu,Tao, Zhanliang,&Chen, Jun.(2014).All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode.journal of the american chemical society,136(47),16461-16464.
MLA Zhu, Zhiqiang,et al."All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode".journal of the american chemical society 136.47(2014):16461-16464.

入库方式: OAI收割

来源:广州能源研究所

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