Fischer Tropsch synthesis from H-2-deficient biosyngas over Mn added Co/SiO2 catalysts
文献类型：期刊论文
| 作者 | Li, Yuping1 ; Qin, Xinxin1; Wang, Tiejun1; Ma, Longlong1; Chen, Lungang1; Tsubaki, Noritatsu2
|
| 刊名 | fuel
 |
| 出版日期 | 2014-11-15 |
| 卷号 | 136页码:130-135 |
| 关键词 | Fischer Tropsch synthesis H-2-deficient biosyngas Co/SiO2 Mn addition |
| 英文摘要 | co/sio2 catalysts with 0.4-7.0 wt.% of mn addition were prepared and evaluated for fischer-tropsch synthesis (fts), using h-2-deficient biosyngas (h-2/co/co2/n-2 = 45/45/7/3, vol%) as feed gas. 0.8 wt.% of mn addition to co/sio2 increased co dispersion and weakened co-si interaction on co-(0.8%) mn/sio2 catalyst. co reducibility was improved to 32.1% and 79.3% at 150-400 degrees c and 150-750 degrees c respectively by h-2-temperature programmed reduction (tpr), which resulted in co conversion of 52.6% and c5+ yield of 43.6% at 24 h time on stream when h-2-deficient biosyngas was used as feed gas for fts. co was further dispersed with low reducibility at higher mn addition amount, which decreased co conversion and favored gaseous hydrocarbon synthesis over co-(2.0%) mn/sio2 and co-(7.0%) mn/sio2. the higher h-2/co usage ratio was obtained over co/sio2 using h-2-deficient biosyngas, compared with that using feed gas with h-2/co ratio of 2.0 over the same catalyst. the existence of small amount of co2 (like 7.0 vol%) in biosyngas might be the main reason to inhibit water gas shift reaction and impel co2 conversion. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | energy & fuels ; engineering, chemical |
| 研究领域[WOS] | energy & fuels ; engineering |
| 关键词[WOS] | manganese oxide ; syngas ; co2 ; hydrocarbons ; promoter ; co/gamma-al2o3 ; hydrogenation ; deactivation ; selectivity ; conversion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000341302300015 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10698]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Toyama Univ, Sch Engn, Dept Appl Chem, Toyama 9308555, Japan |
| 推荐引用方式 GB/T 7714 | Li, Yuping,Qin, Xinxin,Wang, Tiejun,et al. Fischer Tropsch synthesis from H-2-deficient biosyngas over Mn added Co/SiO2 catalysts[J]. fuel,2014,136:130-135. |
| APA | Li, Yuping,Qin, Xinxin,Wang, Tiejun,Ma, Longlong,Chen, Lungang,&Tsubaki, Noritatsu.(2014).Fischer Tropsch synthesis from H-2-deficient biosyngas over Mn added Co/SiO2 catalysts.fuel,136,130-135. |
| MLA | Li, Yuping,et al."Fischer Tropsch synthesis from H-2-deficient biosyngas over Mn added Co/SiO2 catalysts".fuel 136(2014):130-135. |
入库方式： OAI收割
来源：广州能源研究所
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