Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase
文献类型：期刊论文
| 作者 | Wang, Tiejun ; Li, Kai; Liu, Qiying; Zhang, Qing; Qiu, Songbai; Long, Jinxing; Chen, Lungang; Ma, Longlong; Zhang, Qi
|
| 刊名 | applied energy
 |
| 出版日期 | 2014-12-31 |
| 卷号 | 136页码:775-780 |
| 关键词 | Aviation fuel Aqueous phase Catalytic conversion Biomass hydrolysate |
| 英文摘要 | this paper presents a new route for biomass derived aviation fuel synthesis by catalytic conversion in aqueous phase. furfural with the yield of 71% was produced by acid hydrolysis of raw corncob, and hydrogenated to 2-methylfuran with obtaining the yield of 89% over raney ni catalyst, both of which were implemented under mild reaction conditions. the hydroxyalkylation/alkylation condensation of 2-methylfuran and furfural to c-15 intermediate was conducted by using organic and inorganic acid as the catalyst under the reaction condition of 328 k and atmospheric pressure. the maximal 95% of the c-15 intermediate was gained when using sulfuric acid as the catalyst. 83% of liquid alkanes (c-8-c-15) yield and more than 90% of c-14/c-15 selectivity were produced by hydrodeoxygenation of the c-15 intermediate over 10 wt%ni/zro2-sio2 catalyst. during the hydrodeoxygenation process, the catalyst showed excellent stability depended on the 110 h of time-on-stream test, due to its significantly decreased carbon deposition. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | energy & fuels ; engineering, chemical |
| 研究领域[WOS] | energy & fuels ; engineering |
| 关键词[WOS] | renewable diesel ; liquid alkanes ; vegetable-oils ; hydrocarbons ; gas |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000345725800075 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10700]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Tiejun,Li, Kai,Liu, Qiying,et al. Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase[J]. applied energy,2014,136:775-780. |
| APA | Wang, Tiejun.,Li, Kai.,Liu, Qiying.,Zhang, Qing.,Qiu, Songbai.,...&Zhang, Qi.(2014).Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase.applied energy,136,775-780. |
| MLA | Wang, Tiejun,et al."Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase".applied energy 136(2014):775-780. |
入库方式： OAI收割
来源：广州能源研究所
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