热门
Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal-organic frameworks
文献类型：期刊论文
| 作者 | Chen, Jinzhu1 ; Li, Kegui1,3; Chen, Limin2; Liu, Ruliang1,3; Huang, Xing1,2; Ye, Daiqi2
|
| 刊名 | green chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:5页码:2490-2499 |
| 英文摘要 | a series of sulfonic acid-functionalized metal-organic frameworks (mof-so3h) were prepared by postsynthetic modification (psm) of the organic linkers within the mof with chlorosulfonic acid. the obtained mof-so3h, including sulfonic acid-functionalized mil-101(cr) [mil-101(cr)-so3h], uio-66(zr) [uio-66(zr)-so3h], and mil-53(al) [mil-53(al)-so3h], have been systematically studied as solid acids in fructose transformation to 5-hydroxymethylfurfural (hmf). with mil-101(cr)-so3h as catalyst, a hmf yield of 90% with a full fructose conversion was obtained at 120 degrees c for 60 min in dmso. the concentration of -so3h in mof-so3h as well as the contribution of bronsted acidity of mof-so3h parallels its -so3h grafting rate. under a lower -so3h grafting level, a good linear correlation between catalytic activity, in terms of turnover frequency, and sulfonic acid-site density of mof-so3h was found. moreover, the sulfonic acid groups, which function as the catalytic sites, are equivalent in all mof-so3h for fructose-to-hmf transformation, regardless of precursor mofs. both conversions of fructose and selectivities towards hmf increase with the sulfonic acid-site density of mof-so3h at an initial stage of fructose-to-hmf transformation. kinetics studies reveal that the mil-101(cr)-so3h promoted fructose-to-hmf transformation may follow pseudo-first-order kinetics with observed activation energy of 55 kj mol(-1) under the investigated conditions. moreover, mil-101(cr)-so3h behaves as a heterogeneous catalyst and can be easily recovered and reused. the research highlights a good prospect for catalytic application of mof-derived solid acid catalysts for biomass carbohydrate valorization. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ionic liquids ; dehydration ; biomass ; fuels ; chemicals ; efficient ; cellulose ; encapsulation ; kinetics ; mil-101 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000335005200018 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10751]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm & Energy, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jinzhu,Li, Kegui,Chen, Limin,et al. Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal-organic frameworks[J]. green chemistry,2014,16(5):2490-2499. |
| APA | Chen, Jinzhu,Li, Kegui,Chen, Limin,Liu, Ruliang,Huang, Xing,&Ye, Daiqi.(2014).Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal-organic frameworks.green chemistry,16(5),2490-2499. |
| MLA | Chen, Jinzhu,et al."Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal-organic frameworks".green chemistry 16.5(2014):2490-2499. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。